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The Scanning electron microscope (SEM) and Electron-Dispersive Spectroscope (EDS) are two highly effective instruments in the field of nanoscience and nanotechnology. The quality of these instruments is determined by various factors, with…

Applied Physics · Physics 2023-10-24 Hamidreza Moradi , Fatemeh Mehradnia

We study the role of strong electron confinement in surface-enhanced Raman scattering from molecules adsorbed on small noble-metal particles. We describe a new source of Raman signal enhancement which originates from different behavior of…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Vitaliy N. Pustovit , Tigran V. Shahbazyan

Surface-enhanced Raman spectroscopy (SERS) is a sensitive vibrational spectroscopy technique that can enable fast and non-destructive detection of trace molecules. SERS substrates are critical for the advancement of the SERS application. By…

Materials Science · Physics 2020-11-30 Samir Kumar , Takao Fukuoka , Kyoko Namura , Motofumi Suzuki

Two-dimensional (2D) materials, such as graphene and MoS2, have been attracting wide interest in surface enhancement Raman spectroscopy. This perspective gives an overview of recent developments in 2D materials' application in surface…

Materials Science · Physics 2017-07-19 Ming Xia

Photo-Induced Enhanced Raman Spectroscopy (PIERS) is a new surface enhanced Raman spectroscopy (SERS) modality with an order-of-magnitude Raman signal enhancement of adsorbed analytes over that of typical SERS substrates. Despite the…

Materials Science · Physics 2021-06-01 Junzhi Ye , Rakesh Arul , Michel K. Nieuwoudt , Junzhe Dong , Wei Gao , M. Cather Simpson

We demonstrated a highly sensitive, waferscale, highly uniform plasmonic nanomushroom substrate based on plastic for nakedeye plasmonic colorimetry and surface enhanced Raman spectroscopy (SERS). We gave it the name FlexBrite. The dualmode…

In this article, we address the optomechanical effects in surface-enhanced resonant Raman scattering (SERRS) from a single molecule in a nano-particle on mirror (NPoM) nanocavity by developing a quantum master equation theory, which…

The manipulation of nanoscale matter has the potential to revolutionize a variety of fields across nanoscience and technology. Here, we demonstrate experimentally and characterize numerically a device that combines the benefits of…

Mesoscale and Nanoscale Physics · Physics 2024-08-13 Marco Riccardi , Olivier J. F. Martin

We demonstrate fast (0.25 s/pixel) nanoscale chemical imaging in aqueous solution via tip-enhanced Raman scattering (TERS), with sub-15 nm spatial resolution. The substrate consists of 4-mercaptobenzonitrile-functionalized monocrystalline…

Chemical Physics · Physics 2019-03-11 Ashish Bhattarai , Alan G. Joly , Andrey Krayev , Patrick Z. El-Khoury

Noble-metal-free surface-enhanced Raman scattering (SERS) substrates have attracted great attention for their abundant sources, good signal uniformity, superior biocompatibility, and high chemical stability. However, the lack of…

Applied Physics · Physics 2022-04-14 Leilei Lan , Haorun Yao , Guoqun Li , Xingce Fan , Mingze Li , Teng Qiu

The ongoing miniaturization in nanoscience and -technology challenges the sensitivity and selectivity of experimental analysis methods to the ultimate level of single atoms and molecules. A promising new approach, addressed here, focuses on…

Mesoscale and Nanoscale Physics · Physics 2014-03-28 Stefan Müllegger , Stefano Tebi , Amal K. Das , Wolfgang Schöfberger , Felix Faschinger , Reinhold Koch

High resolution nanoscale imaging in liquid environments is crucial for studying molecular interactions in biological and chemical systems. In particular, electron microscopy is the gold-standard tool for nanoscale imaging, but its…

Soft Condensed Matter · Physics 2015-07-20 Wayne Yang , Yuning Zhang , Michael Hilke , Walter Reisner

Impressive advances in nanoscience permit nowadays to manipulate single molecules and broadly control many of their properties. Still, tuning the molecular charge and vibrational properties of single molecules embedded in nanojunctions in…

Chemical Physics · Physics 2015-09-21 Ioan Baldea

Atomically thin boron nitride (BN) nanosheets have been found an excellent substrate for noble metal particles enabled surface enhanced Raman spectroscopy (SERS), thanks to their good adsorption of aromatic molecules, high thermal stability…

Materials Science · Physics 2015-03-13 Qiran Cai , Lu Hua Li , Yuanlie Yu , Yun Liu , Shaoming Huang , Ying Chen , Kenji Watanabe , Takashi Taniguchi

Electrochemical biosensors and the related concept of redox detection at nanogap electrodes are increasingly explored for ultra-sensitive detection of biomolecules. While experimental demonstrations have been encouraging, the associated…

Biological Physics · Physics 2020-01-15 Sanjog V. Joshi , Pradeep R. Nair

Stimulated Raman scattering (SRS) represents a powerful tool for accessing the vibrational properties of molecular compounds or solid state systems. From a spectroscopic perspective, SRS is able to capture Raman spectra free from incoherent…

The vibrational landscape of adsorbed molecules is central to understanding surface interactions at the atomic scale, influencing phenomena from catalysis to molecular electronics. Recent advances in atomic-scale tip-enhanced Raman…

The electronic excitation of molecules triggers diverse phenomena such as luminescence and photovoltaic effects, which are the bases of various energy-converting devices. Understanding and control of the excitations at the single-molecule…

Chemical Physics · Physics 2017-07-12 Hiroshi Imada , Kuniyuki Miwa , Miyabi Imai-Imada , Shota Kawahara , Kensuke Kimura , Yousoo Kim

In this study, we combined the surface-enhanced Raman scattering (SERS) with density functional theory (DFT) calculations to investigate the SERS spectra of lanthanide (Ln)-citrate complexes (Ln = La, Ce, Pr, Nd, Sm, Eu, and Gd) under 488,…

Chemical Physics · Physics 2025-03-25 Hao Jin , Tamitake Itoh , Yuko S. Yamamoto

Solid-state single photon sources (SPSs) with narrow line width play an important role in many leading quantum technologies. Within the wide range of SPSs studied to date, single fluorescent molecules hosted in organic crystals stand out as…