First-principles calculations and a model consideration of magnetically frustrated layered material PdCrO2 are performed. The results on the exchange parameters are in agreement with the experimental data on the Curie-Weiss temperature (θ). We show that experimentally observed strong suppression of the N\'eel temperature (TN) in comparison with the Curie-Weiss temperature is due to three main factors. First, as expected, this is connected with the layered structure and relatively small exchange interaction along the c axis. Second, deformation of the ideal in-plane 120∘ magnetic structure is crucial to provide finite TN value. However, these two factors are still insufficient to explain low TN and the large frustration factor ∣θ∣/TN. Thus, we suggest a scenario of an exotic non-Fermi-liquid state in PdCrO2 above TN within the frameworks of the Anderson lattice model, which seems to explain qualitatively all its main peculiarities.
@article{arxiv.2007.06234,
title = {Unconventional magnetism and electronic state in frustrated layered system PdCrO$_2$},
author = {Evgenia V. Komleva and Valentin Yu. Irkhin and Igor V. Solovyev and Mikhail I. Katsnelson and Sergey V. Streltsov},
journal= {arXiv preprint arXiv:2007.06234},
year = {2020}
}