English

Toy models of multibranched polymers: opened vs. circular structures

Soft Condensed Matter 2022-03-21 v1

Abstract

We study the conformational properties of complex Gaussian polymers containing fcf_c linear branches and frf_r closed loops, periodically tethered at nn branching points to either a linear polymer backbone (generalized bottlebrush structures) or closed polymer ring (decorated ring structure). Applying the path integration method, based on Edwards continuous chain model, we obtain in particular the exact values for the size ratios comparing the gyration radii of considered complex structures and linear chains of the same total molecular weight, as functions of nn, fcf_c and frf_r. Compactification of the overall effective size of branched macromolecules with the increasing number of loops is quantitatively confirmed. Our results are supported by numerical estimates obtained by application of Wei's method.

Keywords

Cite

@article{arxiv.2201.09053,
  title  = {Toy models of multibranched polymers: opened vs. circular structures},
  author = {K. Haydukivska and V. Blavatska},
  journal= {arXiv preprint arXiv:2201.09053},
  year   = {2022}
}
R2 v1 2026-06-24T08:58:35.428Z