English

Hyperbranched polymer stars with Gaussian chain statistics revisited

Soft Condensed Matter 2015-08-18 v1

Abstract

Conformational properties of regular dendrimers and more general hyperbranched polymer stars with Gaussian statistics for the spacer chains between branching points are revisited numerically. We investigate the scaling for asymptotically long chains especially for fractal dimensions df=3d_f = 3 (marginally compact) and df=2.5d_f = 2.5 (diffusion limited aggregation). Power-law stars obtained by imposing the number of additional arms per generation are compared to truly self-similar stars. We discuss effects of weak excluded volume interactions and sketch the regime where the Gaussian approximation should hold in dense solutions and melts for sufficiently large spacer chains.

Keywords

Cite

@article{arxiv.1508.03733,
  title  = {Hyperbranched polymer stars with Gaussian chain statistics revisited},
  author = {P. Polinska and C. Gillig and J. P. Wittmer and J. Baschnagel},
  journal= {arXiv preprint arXiv:1508.03733},
  year   = {2015}
}

Comments

13 pages, 14 figures

R2 v1 2026-06-22T10:34:27.112Z