English

Scaling of Star Polymers with one to 80 Arms

Soft Condensed Matter 2009-11-10 v2 Statistical Mechanics

Abstract

We present large statistics simulations of 3-dimensional star polymers with up to f=80f=80 arms, and with up to 4000 monomers per arm for small values of ff. They were done for the Domb-Joyce model on the simple cubic lattice. This is a model with soft core exclusion which allows multiple occupancy of sites but punishes each same-site pair of monomers with a Boltzmann factor v<1v<1. We use this to allow all arms to be attached at the central site, and we use the `magic' value v=0.6v=0.6 to minimize corrections to scaling. The simulations are made with a very efficient chain growth algorithm with resampling, PERM, modified to allow simultaneous growth of all arms. This allows us to measure not only the swelling (as observed from the center-to-end distances), but also the partition sum. The latter gives very precise estimates of the critical exponents γf\gamma_f. For completeness we made also extensive simulations of linear (unbranched) polymers which give the best estimates for the exponent γ\gamma.

Keywords

Cite

@article{arxiv.cond-mat/0310534,
  title  = {Scaling of Star Polymers with one to 80 Arms},
  author = {Hsiao-Ping Hsu and Walter Nadler and Peter Grassberger},
  journal= {arXiv preprint arXiv:cond-mat/0310534},
  year   = {2009}
}

Comments

7 pages, 7 figures