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Related papers: Scaling of Star Polymers with one to 80 Arms

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We study numerically the effective pair potential between star polymers with equal arm lengths and equal number $f$ of arms. The simulations were done for the soft core Domb-Joyce model on the simple cubic lattice, to minimize corrections…

Soft Condensed Matter · Physics 2009-11-10 Hsiao-Ping Hsu , Peter Grassberger

Star polymer undergoes a transformation from a group of loosely coupled chains at low number of arms to a dense hairy colloid at their high number. This change affects solubility, aggregation and rheological behavior and is of much…

Soft Condensed Matter · Physics 2019-06-20 Ostap Kalyuzhnyi , Khristine Haidukivska , Viktoria Blavatska , Jaroslav Ilnytskyi

By employing monomer-resolved computer simulations and analytical considerations based on polymer scaling theory, we analyze the conformations and interactions of multiarm star polymers strongly adsorbed on a smooth, two-dimensional plane.…

Soft Condensed Matter · Physics 2015-06-15 S. A. Egorov , J. Paturej , C. N. Likos , A. Milchev

A lattice model is presented for the simulation of dynamics in polymeric systems. Each polymer is represented as a chain of monomers, residing on a sequence of nearest-neighbor sites of a face-centered-cubic lattice. The polymers are self-…

Soft Condensed Matter · Physics 2009-11-10 Alexander van Heukelum , G. T. Barkema

Conformational properties of regular dendrimers and more general hyperbranched polymer stars with Gaussian statistics for the spacer chains between branching points are revisited numerically. We investigate the scaling for asymptotically…

Soft Condensed Matter · Physics 2015-08-18 P. Polinska , C. Gillig , J. P. Wittmer , J. Baschnagel

We study uniform 3-star polymers with one branch tethered to an attractive surface and another branch pulled by a force away from the surface. Each branch of the 3-star lattice is modelled as a self-avoiding walk on the simple cubic lattice…

Statistical Mechanics · Physics 2019-05-30 C J Bradly , A L Owczarek

Single-chain Monte Carlo simulations of amphiphilic diblock star copolymers were carried out in continuous space using implicit solvents. Two distinct architectures were studied: stars with the hydrophobic blocks attached to the core, and…

Soft Condensed Matter · Physics 2009-11-10 Ronan Connolly , Edward G. Timoshenko , Yuri A. Kuznetsov

We analyze the effect of polydispersity in the arm number on the effective interactions, structural correlations and the phase behavior of star polymers in a good solvent. The effective interaction potential between two star polymers with…

Soft Condensed Matter · Physics 2009-10-31 Christian von Ferber , Arben Jusufi , Martin Watzlawek , Christos N. Likos , Hartmut Lowen

The scaling behaviour of randomly branched polymers in a good solvent is studied in two to nine dimensions, using as microscopic models lattice animals and lattice trees on simple hypercubic lattices. As a stochastic sampling method we use…

Statistical Mechanics · Physics 2009-11-10 Hsiao-Ping Hsu , Walter Nadler , Peter Grassberger

Fujiyabu et al. have experimentally reported that mixing of 3-arm star prepolymers into 4-arm analog improves the toughness of the resultant polymer networks compared to the base network composed of 4-arm star polymers only. For the…

Soft Condensed Matter · Physics 2024-06-17 Yuichi Masubuchi

We consider a coarse-grained (CG) model with pairwise interactions, suitable to describe low-density solutions of star-branched polymers of functionality $f$. Each macromolecule is represented by a CG molecule with $(f+1)$ interaction…

Soft Condensed Matter · Physics 2017-08-02 Roberto Menichetti , Andrea Pelissetto , Ferdinando Randisi

Using monomer-resolved Molecular Dynamics simulations and theoretical arguments based on the radial dependence of the osmotic pressure in the interior of a star, we systematically investigate the effective interactions between hard,…

Soft Condensed Matter · Physics 2009-10-31 A. Jusufi , J. Dzubiella , C. N. Likos , C. von Ferber , H. Loewen

We implement parallel versions of the GARM and Wang-Landau algorithms for stars and for acyclic uniform branched networks in the square lattice. These are models of monodispersed branched polymers, and we estimate the star vertex exponents…

Statistical Mechanics · Physics 2021-06-02 S Campbell , EJ Janse van Rensburg

The phase diagram of star polymer solutions in a good solvent is obtained over a wide range of densities and arm numbers by Monte Carlo simulations. The effective interaction between the stars is modeled by an ultrasoft pair potential which…

Soft Condensed Matter · Physics 2009-10-31 M. Watzlawek , C. N. Likos , H. Loewen

The reaction of $AB_m$ monomers (m=2,3) with a multifunctional B_f-type polymer chain ("hypergrafting") is studied by coarse-grained molecular dynamics simulations. The $AB_m$ monomers are hypergrafted using the slow monomer addition…

Soft Condensed Matter · Physics 2015-11-09 Hauke Rabbel , Holger Frey , Friederike Schmid

We analyze the effective triplet interactions between the centers of star polymers in a good solvent. Using an analytical short distance expansion inspired by scaling theory, we deduce that the triplet part of the three-star force is…

Soft Condensed Matter · Physics 2015-06-24 Christian von Ferber , Arben Jusufi , Christos N. Likos , Hartmut Lowen , Martin Watzlawek

We revisit an integrable lattice model of polymer collapse using numerical simulations. This model was first studied by Bl\"ote and Nienhuis in J. Phys. A. {\bf 22}, 1415 (1989) and it describes polymers with some attraction, providing thus…

Statistical Mechanics · Physics 2015-06-12 A. Bedini , A. L. Owczarek , T. Prellberg

Bottle brushes are polymeric macromolecules made of a linear polymeric backbone grafted with side chains. The choice of the grafting density {\sigma}g, the length ns the grafted side chains and their chemical nature fully determines the…

Soft Condensed Matter · Physics 2019-08-09 P. Corsi , E. Roma , T. Gasperi , F. Bruni , B. Capone

We consider a lattice model of a mixture of repulsive, attractive, or neutral monodisperse star (species A) and linear (species B) polymers with a third monomeric species C, which may represent free volume. The mixture is next to a hard,…

Soft Condensed Matter · Physics 2009-11-13 Richard Batman , P. D. Gujrati

Single three dimensional polymers confined to a slab, i.e. to the region between two parallel plane walls, are studied by Monte Carlo simulations. They are described by $N$-step walks on a simple cubic lattice confined to the region $1 \le…

Soft Condensed Matter · Physics 2009-11-10 Hsiao-Ping Hsu , Peter Grassberger
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