English

Conformation and topology of cyclical star polymers

Soft Condensed Matter 2024-09-04 v1 Statistical Mechanics

Abstract

We study the conformation and topological properties of cyclical star polymers with ff ring arms, each made of nn beads. We find that the conformational properties of unlinked cyclical star polymers are compatible to those of linear star polymers with 2f2f arms made of n/2n/2 beads each. This compatibility vanishes when the topology of the star, measured as the degree of linking between arms, changes. In fact, when links are allowed we notice that the gyration radius decreases as a function of the absolute linking number Lk\vert Lk \vert of the arms, regardless of the protocol that is employed to introduce said links. Furthermore, the internal structure of the macromolecules, as highlighted by the radial density function, changes qualitatively for large values of Lk\vert Lk \vert.

Keywords

Cite

@article{arxiv.2409.01149,
  title  = {Conformation and topology of cyclical star polymers},
  author = {Davide Breoni and Emanuele Locatelli and Luca Tubiana},
  journal= {arXiv preprint arXiv:2409.01149},
  year   = {2024}
}

Comments

11 pages, 11 figures