English

Suppression of inelastic collisions of polar $^1 \Sigma$ state molecules in an electrostatic field

Atomic Physics 2016-09-08 v1

Abstract

Collisions of polar 1Σ^{1}\Sigma state molecules at ultralow energies are considered, within a model that accounts for long-range dipole-dipole interactions, plus rotation of the molecules. We predict a substantial suppression of dipole-driven inelastic collisions at high values of the applied electric field, namely, field values of several times Be/μB_e/\mu. Here BeB_e is the rotational constant, and μ\mu is the electric dipole moment of molecules. The sudden large drop in the inelastic cross section is attributed to the onset of degeneracy between molecular rotational levels, which dramatically alters the scattering Hamiltonian. As a result of the large ratio of elastic to inelastic collision rates, we predict that evaporative cooling may be feasible for 1Σ^{1}\Sigma state molecules in weak-field-seeking states, provided a large bias electric field is present.

Keywords

Cite

@article{arxiv.physics/0507077,
  title  = {Suppression of inelastic collisions of polar $^1 \Sigma$ state molecules in an electrostatic field},
  author = {Alexander V. Avdeenkov and Masatoshi Kajita and John L. Bohn},
  journal= {arXiv preprint arXiv:physics/0507077},
  year   = {2016}
}