Elastic and inelastic collisions of $^2\Sigma$ molecules in a magnetic field
Abstract
We calculate the cross sections for elastic scattering and Zeeman relaxation in binary collisions of molecules in the ro-vibrational ground state of a electronic state and the Zeeman state with the electron spin projection on the magnetic field axis. This is the lowest-energy state of molecules confined in a magnetic trap. The results are averaged over calculations with multiple molecule - molecule interaction potentials, which yields the expectation intervals for the cross sections and the elastic-to-inelastic cross section ratios. We find that the elastic-to-inelastic cross section ratios under conditions corresponding to trapped molecular ensembles at K exceed 100 for the majority of molecules. The range of molecules expected to be collisionally unstable in magnetic traps at K is limited to molecules with the spin-rotation interaction constant cm and the rotational constant cm.
Keywords
Cite
@article{arxiv.1308.0771,
title = {Elastic and inelastic collisions of $^2\Sigma$ molecules in a magnetic field},
author = {Jie Cui and Roman V. Krems},
journal= {arXiv preprint arXiv:1308.0771},
year = {2015}
}