English

Elastic and inelastic collisions of $^2\Sigma$ molecules in a magnetic field

Chemical Physics 2015-06-16 v1 Atomic Physics Quantum Physics

Abstract

We calculate the cross sections for elastic scattering and Zeeman relaxation in binary collisions of molecules in the ro-vibrational ground state of a 2Σ^2\Sigma electronic state and the Zeeman state with the electron spin projection MS=1/2M_S=1/2 on the magnetic field axis. This is the lowest-energy state of 2Σ^2\Sigma molecules confined in a magnetic trap. The results are averaged over calculations with multiple molecule - molecule interaction potentials, which yields the expectation intervals for the cross sections and the elastic-to-inelastic cross section ratios. We find that the elastic-to-inelastic cross section ratios under conditions corresponding to trapped molecular ensembles at T103T \sim 10^{-3} K exceed 100 for the majority of 2Σ^2\Sigma molecules. The range of 2Σ^2\Sigma molecules expected to be collisionally unstable in magnetic traps at T<103T < 10^{-3} K is limited to molecules with the spin-rotation interaction constant γSR>0.5\gamma_{\rm SR} > 0.5 cm1^{-1} and the rotational constant Be<4B_e < 4 cm1^{-1}.

Keywords

Cite

@article{arxiv.1308.0771,
  title  = {Elastic and inelastic collisions of $^2\Sigma$ molecules in a magnetic field},
  author = {Jie Cui and Roman V. Krems},
  journal= {arXiv preprint arXiv:1308.0771},
  year   = {2015}
}