Kagome metals are widely recognized as versatile platforms for exploring novel topological properties, unconventional electronic correlations, magnetic frustration, and superconductivity. In the RV6Sn6 family of materials (R = Sc, Y, Lu), ScV6Sn6 hosts an unusual charge density wave ground state as well as structural similarities with the AV3Sb5 system (A = K, Cs, Rb). In this work, we combine Raman scattering spectroscopy with first-principles lattice dynamics calculations to reveal the charge density wave state in ScV6Sn6. In the low temperature phase, we find a five-fold splitting of the V-containing totally symmetric mode near 240 cm−1 suggesting that the density wave acts to mix modes of P6/mmm and R3ˉm symmetry - an effect that we quantify by projecting phonons of the high symmetry state onto those of the lower symmetry structure. We also test the stability of the density wave state under compression and find that both physical and chemical pressure act to quench the effect. We discuss these findings in terms of symmetry and the structure-property trends that can be unraveled in this system.
@article{arxiv.2305.01086,
title = {Origin and stability of the charge density wave in ScV$_6$Sn$_6$},
author = {Yanhong Gu and Ethan Ritz and William R. Meier and Avery Blockmon and Kevin Smith and Richa Pokharel Madhogaria and Shirin Mozaffari and David Mandrus and Turan Birol and Janice L. Musfeldt},
journal= {arXiv preprint arXiv:2305.01086},
year = {2023}
}