Orbital-selective band modifications in a charge-ordered kagome metal LuNb$_6$Sn$_6$
Abstract
The origin of the charge order in kagome lattice materials has attracted great interest due to the unique electronic structure features connected to kagome networks and the interplay between electron and lattice degrees of freedom. Recently, compounds with composition NbSn ( = Ce-Nd, Sm, Gd-Tm, Lu, Y) appear as a new family of kagome metals, structurally analogous to VSn ( = Sc, Y, or rare earth) systems. Among them, LuNbSn emerges as a novel material hosting charge density wave (CDW) with a wave vector, akin to that in ScVSn. Here, we employ high-resolution angle-resolved photoemission spectroscopy, scanning tunneling microscopy, and density functional theory calculations to systematically investigate the electronic properties of LuNbSn. Our observation reveals the characteristic band structures of the "166" kagome system. A charge instability driven by Fermi surface nesting is decisively ruled out through an analysis of the interactions between van Hove singularities. Across the CDW transition, we observe orbital-selective band modifications, with noticeable evolutions of Lu 5 and Sn 5 electrons, while Nb 4 electrons exhibit minimal change, suggesting that the Lu and Sn sites other than the Nb kagome lattice play a key role in the formation of CDW. Our findings substantiate a universal lattice-driven CDW mechanism rather than a charge-instability-driven one in the "166" kagome compounds, making it a distinct material class compared to other charge-ordered kagome systems, such as VSb ( = K, Rb, Cs) and FeGe.
Keywords
Cite
@article{arxiv.2504.04019,
title = {Orbital-selective band modifications in a charge-ordered kagome metal LuNb$_6$Sn$_6$},
author = {Rui Lou and Yumeng Zhang and Erjian Cheng and Xiaolong Feng and Alexander Fedorov and Zongkai Li and Yixuan Luo and Alexander Generalov and Haiyang Ma and Quanxing Wei and Yi Zhou and Susmita Changdar and Walter Schnelle and Dong Chen and Yulin Chen and Jianpeng Liu and Yanfeng Guo and Sergey Borisenko and Denis V. Vyalikh and Claudia Felser and Bernd Büchner and Zhongkai Liu},
journal= {arXiv preprint arXiv:2504.04019},
year = {2025}
}
Comments
17 pages, 4 figures