Multidimensional spectroscopy with a single broadband phase-shaped laser pulse
Chemical Physics
2015-06-22 v1 Optics
Abstract
We calculate the frequency-dispersed nonlinear transmission signal of a phase-shaped visible pulse to fourth order in the field. Two phase profiles, a phase-step and phase-pulse, are considered. Two dimensional signals obtained by varying the detected frequency and phase parameters are presented for a three electronic band model system. We demonstrate how two-photon and stimulated Raman resonances can be manipulated by the phase profile and sign, and selected quantum pathways can be suppressed.
Cite
@article{arxiv.1408.2174,
title = {Multidimensional spectroscopy with a single broadband phase-shaped laser pulse},
author = {Rachel Glenn and Shaul Mukamel},
journal= {arXiv preprint arXiv:1408.2174},
year = {2015}
}
Comments
26 pages, 15 figures