Raman spectroscopy examination of the 25 deg-C water freezing under compression revealed transition from 1.35 GPa to 0.86 GPa upon ice being formed at continued volume change. The transition is associated with a slight blue shift of the high-frequency phonon (omiga_H ~ 3120 cm-1) and creation of the low-frequency phonons (Omiga_L ~ 200 cm-1). In the liquid and in the solid phase, the increased pressure softens the Omiga_H and stiffens the Omida_L, which indicates the presence of the inter-electron-pair repulsion in both liquid and solid water.
@article{arxiv.1310.1441,
title = {Mechano-freezing of the ambient water},
author = {Xi Zhang and Tingting Yan and Bo Zou and Chang Q Sun},
journal= {arXiv preprint arXiv:1310.1441},
year = {2013}
}