English

Solid liquid phase changes with different densities

Analysis of PDEs 2014-01-10 v1 Statistical Mechanics Mathematical Physics Classical Analysis and ODEs math.MP

Abstract

In this paper we present a new thermodynamically consistent phase transition model describing the evolution of a liquid substance, e.g., water, in a rigid container Ω\Omega when we freeze the container. Since the density ϱ2\varrho_{2} of ice with volume fraction β2\beta_{2}, is lower than the density ϱ1\varrho_{1} of water with volume fraction β1\beta_{1}, experiments - for instance the freezing of a glass bottle filled with water - show that the water pressure increases up to the rupture of the bottle. When the container is not impermeable, freezing may produce a non-homogeneous material, for instance water ice or sorbet. Here we describe a general class of phase transition processes including this example as particular case. Moreover, we study the resulting nonlinear and singular PDE system from the analytical viewpoint recovering existence of a global (in time) weak solution and also uniqueness for some particular choices of the nonlinear functions involved.

Keywords

Cite

@article{arxiv.0806.2915,
  title  = {Solid liquid phase changes with different densities},
  author = {Michel Fremond and Elisabetta Rocca},
  journal= {arXiv preprint arXiv:0806.2915},
  year   = {2014}
}
R2 v1 2026-06-21T10:51:46.964Z