Causes of high-temperature superconductivity in the hydrogen sulfide electron-phonon system
Superconductivity
2015-07-22 v1 Materials Science
Abstract
The electron and phonon spectra, as well as the density of electron and phonon states of the stable orthorhombic structure of hydrogen sulfide (SH2) at pressures 100-180 GPa have been calculated. It is found that the set of parallel planes of hydrogen atoms is formed at pressure ~175 GPa as a result of structural changes in the unit cell of the crystal under pressure. There should be complete concentration of hydrogen atoms in these planes. As a result the electron properties of the system acquire a quasi-two-dimensional character. The features of in phase and antiphase oscillations of hydrogen atoms in these planes leading to two narrow high-energy peaks in the phonon density of states are investigated.
Keywords
Cite
@article{arxiv.1507.05749,
title = {Causes of high-temperature superconductivity in the hydrogen sulfide electron-phonon system},
author = {Nikolay Degtyarenko and Evgeny Mazur},
journal= {arXiv preprint arXiv:1507.05749},
year = {2015}
}