English

$\mathrm{La}_{\mathrm{1-}x} \mathrm{Mn}_{\mathrm{1-}y} \mathrm{O}_{\mathrm{1\pm}\delta}$ buffer layers on inclined substrate deposited MgO templates for coated conductors

Superconductivity 2020-12-03 v1 Materials Science

Abstract

Most commercial high-temperature superconducting coated conductors based on ion beam assisted MgO deposited templates use LaMnO3\mathrm{LaMnO_3} (LMO) films as the terminating buffer layer. In contrast, coated conductors based on inclined substrate deposition (ISD)-MgO technology are still produced with homoepitaxial (homoepi)-MgO as the cap layer. In this work we report on the deposition of LMO buffer layers on ISD-MgO/homoepi-MgO by electron beam physical vapor deposition. The growth parameters of textured LMO films were studied systematically and their properties were optimized regarding the critical current densitiy (JcJ_\mathrm{c}) of the subsequently deposited DyBa2Cu3O7δ\mathrm{DyBa_2Cu_3O}_{\mathrm{7-}\delta} (DyBCO) superconducting films. LMO films without outgrowths at the surface were obtained at growth rates of up to 4A˚/s4\,\mathrm{\r{A}/s}. Despite the formation of non-stoichiometric LMO films containing 59%59\,\% La, single-phase films were obtained at substrate temperatures below 775C775^{\circ}\mathrm{C} and at oxygen partial pressures of up to 4×104mbar4\times10^{-4}\,\mathrm{mbar} due to a large homogeneity region towards La. The JcJ_\mathrm{c} values of DyBCO films deposited on LMO were found to be independent of the LMO thickness in a range from 50nm50\,\mathrm{nm} to 450nm450\,\mathrm{nm}. DyBCO films on LMO reach Jc=0.83MA/cm2J_\mathrm{c}=0.83\,\mathrm{MA/cm^2} at 77K77\,\mathrm{K} in zero applied field. This value is up to 30%30\,\% higher than those of DyBCO films grown directly on homoepi-MgO. The wide range of LMO growth parameters and higher JcJ_\mathrm{c} values of DyBCO on LMO compared to DyBCO on homoepi-MgO make this material attractive for its use in manufacturing coated conductors based on ISD-MgO technology.

Keywords

Cite

@article{arxiv.2012.01318,
  title  = {$\mathrm{La}_{\mathrm{1-}x} \mathrm{Mn}_{\mathrm{1-}y} \mathrm{O}_{\mathrm{1\pm}\delta}$ buffer layers on inclined substrate deposited MgO templates for coated conductors},
  author = {Oleksiy Troshyn and Christian Hoffmann and Veit Große and Jens Hänisch and Lucas Becker and Rudolf Gross},
  journal= {arXiv preprint arXiv:2012.01318},
  year   = {2020}
}

Comments

11 pages, 12 figures