English

Erbium location into AlN films as probed by spatial resolution experimental techniques

Materials Science 2019-11-18 v1

Abstract

This paper presents a thorough experimental investigation of erbium-doped aluminium nitride thin films prepared by R.F. magnetronsputtering, coupling Scanning Transmission Electron Microscopy X-ray-mapping imagery, conventional Transmission Electron Microscopy and X-ray diffraction. The study is an attempt of precise localisation of the rare earth atoms inside the films and in the hexagonal w{\"u}rtzite unit cell.The study shows that AlN:Erx is a solid solution even when x reaches 6 at.%, and does not lead to the precipitation of erbium rich phases. The X-ray diffraction measurements completed by simulation show that the main location of erbium in the AlN w{\"u}rtzite is the metal substitution site on the whole range. They also show that octahedral and tetrahedral sites of the w{\"u}rtzite do welcome Er ions over the [1.6--6%] range. The XRD deductions allow some interpretations on the theoretical mechanisms of the photoluminescence mechanisms and more specifically on their concentration quenching.

Keywords

Cite

@article{arxiv.1911.06694,
  title  = {Erbium location into AlN films as probed by spatial resolution experimental techniques},
  author = {Valerie Brien and Pascal Boulet},
  journal= {arXiv preprint arXiv:1911.06694},
  year   = {2019}
}
R2 v1 2026-06-23T12:17:14.547Z