English

Electron-phonon interaction in the solid form of the smallest fullerene C$_{20}$

Materials Science 2009-11-07 v1 Superconductivity

Abstract

The electron-phonon coupling of a theoretically devised carbon phase made by assembling the smallest fullerenes C20_{20} is calculated from first principles. The structure consists of C20_{20} cages in an {\it fcc} lattice interlinked by two bridging carbon atoms in the interstitial tetrahedral sites ({\it fcc}-C22_{22}). The crystal is insulating but can be made metallic by doping with interstitial alkali atoms. In the compound NaC22_{22} the calculated coupling constant λ/N(0)\lambda/N(0) is 0.28 eV, a value much larger than in C60_{60}, as expected from the larger curvature of C20_{20}. On the basis of the McMillan's formula, the calculated λ\lambda=1.12 and a μ\mu^* assumed in the range 0.3-0.1 a superconducting Tc_c in the range 15-55 K is predicted.

Keywords

Cite

@article{arxiv.cond-mat/0203185,
  title  = {Electron-phonon interaction in the solid form of the smallest fullerene C$_{20}$},
  author = {I. Spagnolatti and M. Bernasconi and G. Benedek},
  journal= {arXiv preprint arXiv:cond-mat/0203185},
  year   = {2009}
}

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7 pages