The electron-phonon coupling of a theoretically devised carbon phase made by assembling the smallest fullerenes C20 is calculated from first principles. The structure consists of C20 cages in an {\it fcc} lattice interlinked by two bridging carbon atoms in the interstitial tetrahedral sites ({\it fcc}-C22). The crystal is insulating but can be made metallic by doping with interstitial alkali atoms. In the compound NaC22 the calculated coupling constant λ/N(0) is 0.28 eV, a value much larger than in C60, as expected from the larger curvature of C20. On the basis of the McMillan's formula, the calculated λ=1.12 and a μ∗ assumed in the range 0.3-0.1 a superconducting Tc in the range 15-55 K is predicted.
@article{arxiv.cond-mat/0203185,
title = {Electron-phonon interaction in the solid form of the smallest fullerene C$_{20}$},
author = {I. Spagnolatti and M. Bernasconi and G. Benedek},
journal= {arXiv preprint arXiv:cond-mat/0203185},
year = {2009}
}