English

Electron-phonon interaction in C70

Condensed Matter 2009-10-31 v1

Abstract

The matrix elements of the deformation potential of C70_{70} are calculated by means of a simple, yet accurate solution of the electron-phonon coupling problem in fullerenes, based on a parametrization of the ground state electronic density of the system in terms of sp2+xsp^{2+x} hybridized orbitals. The value of the calculated dimensionless total electron-phonon coupling constant is λ0.1\lambda\approx0.1, an order of magnitude smaller than in C60_{60}, consistent with the lack of a superconducting phase transition in C70_{70}A3_3 fullerite, and in overall agreement with measurements of the broadening of Raman peaks in C70_{70}K4_4. We also calculate the photoemission cross section of C70_{70}^-, which is found to display less structure than that associated with C60_{60}^-, in overall agreement with the experimental findings.

Keywords

Cite

@article{arxiv.cond-mat/0001047,
  title  = {Electron-phonon interaction in C70},
  author = {D. Provasi and N. Breda and R. A. Broglia and G. Colo` and H. E. Roman and G. Onida},
  journal= {arXiv preprint arXiv:cond-mat/0001047},
  year   = {2009}
}

Comments

To be published in Phys. Rev. B