English

Disordered ground state in the three-dimensional face-centred frustrated spin-$\frac{5}{2}$ system MnSn(OH)$_\text{6}$

Strongly Correlated Electrons 2025-08-08 v2

Abstract

Frustrated magnetism in face-centred cubic (fcc) magnetic sublattices remains underexplored but holds considerable potential for exotic magnetic behaviour. Here we report on the crystal structure, magnetic and thermodynamic properties of the AA-site-vacant double hydroxide perovskite MnSn(OH)6_6. Despite dominant antiferromagnetic interactions among Mn2+^{2+} moments, evidenced by a negative Curie-Weiss temperature, the lack of a sharp thermodynamic transition down to 350\,mK implies the absence of long-range magnetic order. However, a broad hump in the specific heat at 1.6\,K suggests short-range correlations. Neutron diffraction at low temperatures confirms the presence of three-dimensional antiferromagnetic correlations, manifested as diffuse magnetic scattering with a correlation length ξ=24.66\xi = 24.66\,{\AA} and magnetic propagation vectors k=(121212)\mathbf{k}=(\frac{1}{2}\,\frac{1}{2}\,\frac{1}{2}) and (00.6250)(0\,0.625\,0) at 20\,mK.

Keywords

Cite

@article{arxiv.2502.12433,
  title  = {Disordered ground state in the three-dimensional face-centred frustrated spin-$\frac{5}{2}$ system MnSn(OH)$_\text{6}$},
  author = {Kaushick K. Parui and Anton A. Kulbakov and Ellen Häußler and Nikolai S. Pavlovskii and Aswathi Mannathanath Chakkingal and Maxim Avdeev and Roman Gumeniuk and Sergey Granovsky and Alexander Mistonov and Sergei A. Zvyagin and Thomas Doert and Dmytro S. Inosov and Darren C. Peets},
  journal= {arXiv preprint arXiv:2502.12433},
  year   = {2025}
}

Comments

11 pages, 6 figures. CIF files included as arXiv ancillary files