Perovskite iridates of 6H hexagonal structure present a plethora of possibilities in terms of the variety of ground states resulting from a competition between spin-orbit coupling (SOC), hopping, noncubic crystal field (ΔCFENC) and superexchange energy scales within the Ir2O9 dimers. Here we have investigated one such compound Ba3CdIr2O9 by x-ray diffraction, dc magnetic susceptibility(χ), heat capacity(Cp) and also 113Cd nuclear magnetic resonance (NMR) spectroscopy. We have established that the magnetic ground state has a small but finite magnetic moment on Ir5+ in this system, which likely arises from intradimer Ir-Ir hopping and local crystal distortions. Our heat capacity, NMR, and dc magnetic susceptibility measurements further rule out any kind of magnetic long-/short-range ordering among the Ir moments down to at least 2K. In addition, the magnetic heat capacity data shows linear temperature dependence at low temperatures under applied high fields (> 30 kOe), suggesting gapless spin-density of states in the compound.
@article{arxiv.1908.05163,
title = {Magnetic ground state of distorted 6H perovskite Ba$_3$CdIr$_2$O$_9$},
author = {Md Salman Khan and Abhisek Bandyopadhyay and Abhishek Nag and Vinod Kumar and A. V. Mahajan and Sugata Ray},
journal= {arXiv preprint arXiv:1908.05163},
year = {2019}
}