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Magnetic ground state of distorted 6H perovskite Ba$_3$CdIr$_2$O$_9$

Strongly Correlated Electrons 2019-08-15 v1

Abstract

Perovskite iridates of 6H hexagonal structure present a plethora of possibilities in terms of the variety of ground states resulting from a competition between spin-orbit coupling (SOC), hopping, noncubic crystal field (ΔCFENC\Delta_{CFE}^{NC}) and superexchange energy scales within the Ir2_2O9_9 dimers. Here we have investigated one such compound Ba3_3CdIr2_2O9_9 by x-ray diffraction, dc magnetic susceptibility(χ\chi), heat capacity(CpC_p) and also 113{}^{113}Cd nuclear magnetic resonance (NMR) spectroscopy. We have established that the magnetic ground state has a small but finite magnetic moment on Ir5+^{5+} in this system, which likely arises from intradimer Ir-Ir hopping and local crystal distortions. Our heat capacity, NMR, and dc magnetic susceptibility measurements further rule out any kind of magnetic long-/short-range ordering among the Ir moments down to at least 2K. In addition, the magnetic heat capacity data shows linear temperature dependence at low temperatures under applied high fields (>> 30 kOe), suggesting gapless spin-density of states in the compound.

Keywords

Cite

@article{arxiv.1908.05163,
  title  = {Magnetic ground state of distorted 6H perovskite Ba$_3$CdIr$_2$O$_9$},
  author = {Md Salman Khan and Abhisek Bandyopadhyay and Abhishek Nag and Vinod Kumar and A. V. Mahajan and Sugata Ray},
  journal= {arXiv preprint arXiv:1908.05163},
  year   = {2019}
}

Comments

2 Tables, 5 figures