Diffusion of a ring polymer in good solution via the Brownian dynamics
Soft Condensed Matter
2009-11-13 v2
Abstract
Diffusion constants D_{R} and D_{L} of ring and linear polymers of the same molecular weight in a good solvent, respectively, have been evaluated through the Brownian dynamics with hydrodynamic interaction. The ratio , which should be universal in the context of the renormalization group, has been estimated as for the large-N limit. It should be consistent with that of synthetic polymers, while it is smaller than that of DNAs such as . Furthermore, the probability of the ring polymer being a nontrivial knot is found to be very small, while bond crossings may occur at almost all time steps in the present simulation that realizes the good solvent conditions.
Cite
@article{arxiv.0708.1397,
title = {Diffusion of a ring polymer in good solution via the Brownian dynamics},
author = {Naoko Kanaeda and Tetsuo Deguchi},
journal= {arXiv preprint arXiv:0708.1397},
year = {2009}
}
Comments
11 pages, 4 figures