English

Diffusion of a ring polymer in good solution via the Brownian dynamics

Soft Condensed Matter 2009-11-13 v2

Abstract

Diffusion constants D_{R} and D_{L} of ring and linear polymers of the same molecular weight in a good solvent, respectively, have been evaluated through the Brownian dynamics with hydrodynamic interaction. The ratio C=DR/DLC=D_{R}/D_{L}, which should be universal in the context of the renormalization group, has been estimated as C=1.11±0.01C= 1.11 \pm 0.01 for the large-N limit. It should be consistent with that of synthetic polymers, while it is smaller than that of DNAs such as C1.3C \approx 1.3. Furthermore, the probability of the ring polymer being a nontrivial knot is found to be very small, while bond crossings may occur at almost all time steps in the present simulation that realizes the good solvent conditions.

Keywords

Cite

@article{arxiv.0708.1397,
  title  = {Diffusion of a ring polymer in good solution via the Brownian dynamics},
  author = {Naoko Kanaeda and Tetsuo Deguchi},
  journal= {arXiv preprint arXiv:0708.1397},
  year   = {2009}
}

Comments

11 pages, 4 figures

R2 v1 2026-06-21T09:06:25.162Z