English

Self diffusion in a system of interacting Langevin particles

Soft Condensed Matter 2009-11-10 v1 Statistical Mechanics

Abstract

The behavior of the self diffusion constant of Langevin particles interacting via a pairwise interaction is considered. The diffusion constant is calculated approximately within a perturbation theory in the potential strength about the bare diffusion constant. It is shown how this expansion leads to a systematic double expansion in the inverse temperature β\beta and the particle density ρ\rho. The one-loop diagrams in this expansion can be summed exactly and we show that this result is exact in the limit of small β\beta and ρβ\rho\beta constant. The one-loop result can also be re-summed using a semi-phenomenological renormalization group method which has proved useful in the study of diffusion in random media. In certain cases the renormalization group calculation predicts the existence of a diverging relaxation time signalled by the vanishing of the diffusion constant -- possible forms of divergence coming from this approximation are discussed. Finally, at a more quantitative level, the results are compared with numerical simulations, in two-dimensions, of particles interacting via a soft potential recently used to model the interaction between coiled polymers.

Keywords

Cite

@article{arxiv.cond-mat/0401421,
  title  = {Self diffusion in a system of interacting Langevin particles},
  author = {D. S. Dean and A. Lefèvre},
  journal= {arXiv preprint arXiv:cond-mat/0401421},
  year   = {2009}
}

Comments

12 pages, 8 figures .eps

R2 v1 2026-07-22T10:59:01.178Z