English

Enhanced particle diffusion in fluctuating binary environments

Chemical Physics 2025-12-03 v1 Soft Condensed Matter

Abstract

We investigate single-particle diffusion in a two-state Langevin model where the friction coefficient randomly switches between low-friction (liquid-like) and high-friction (glassy-like) states. The dynamics are governed by the ratio between the friction switching time τ\tau and the intrinsic velocity relaxation time τ0\tau_0. For fast switching (τ/τ01\tau/\tau_0 \lesssim 1) the motion is homogeneous and Brownian, whereas for slow switching (τ/τ01\tau/\tau_0 \gg 1) the particle exhibits intermittent dynamics and an enhanced diffusion coefficient. Analysis of the single-particle overlap function Q(t)Q(t) and the dynamic susceptibility χ4(t)\chi_4(t) reveals decoupling of the diffusion coefficient from the average friction upon cooling, which coincides with increasing temporal dynamic heterogeneity. This minimal model provides a transparent framework for understanding single-particle transport in media with fluctuating local mobility, including supercooled liquids and phase-separated soft materials.

Keywords

Cite

@article{arxiv.2512.02776,
  title  = {Enhanced particle diffusion in fluctuating binary environments},
  author = {Fivos Perakis and Takeshi Kawasaki and Shinji Saito},
  journal= {arXiv preprint arXiv:2512.02776},
  year   = {2025}
}