English

Critical slowing down in thermal soft-sphere glasses via energy minimization

Soft Condensed Matter 2024-04-17 v2

Abstract

Using hybrid molecular dynamics/SWAP Monte Carlo (MD/SMC) simulations, we show that the terminal relaxation times τ\tau for FIRE energy minimization of soft-sphere glasses exhibit thermal onset as samples become increasingly well-equilibrated. Although τ(ϕ)\tau(\phi) can decrease by orders of magnitude as equilibration proceeds and the jamming density ϕJ\phi_{\rm J} increases via thermal onset, it always scales as τ(ϕ)(ϕJϕ)2[ZisoZms(τ)]2\tau(\phi) \sim (\phi_{\rm J} - \phi)^{-2} \sim [Z_{\rm iso} - Z_{\rm ms}(\tau)]^{-2}, where ϕJ\phi_{\rm J} is the jamming density and Zms(τ)Z_{\rm ms}(\tau) is the average coordination number of particles satisfying a minimal local mechanical stability criterion (Zd+1Z \geq d+1) at the top of the final potential-energy-landscape (PEL) sub-basin the system encounters. This scaling allows us to collapse τ\tau datasets that look very different when plotted as a function of ϕ\phi, and to address a closely related question: how does the character of the PEL basins that dense thermal glasses most typically occupy evolve as the glasses age at constant ϕ\phi and TT?

Keywords

Cite

@article{arxiv.2312.13466,
  title  = {Critical slowing down in thermal soft-sphere glasses via energy minimization},
  author = {Kevin A. Interiano-Alberto and Peter K. Morse and Robert S. Hoy},
  journal= {arXiv preprint arXiv:2312.13466},
  year   = {2024}
}

Comments

resubmitted in response to referee comments