English

Shape universality classes in the random sequential addition of non-spherical particles

Statistical Mechanics 2017-07-24 v2 Soft Condensed Matter

Abstract

Random sequential addition (RSA) models are used in a large variety of contexts to model particle aggregation and jamming. A key feature of these models is the algebraic time dependence of the asymptotic jamming coverage as tt\to\infty. For the RSA of monodisperse non-spherical particles the scaling is generally believed to be  tν~t^{-\nu}, where ν=1/df\nu=1/d_{\rm f} for a particle with dfd_{\rm f} degrees of freedom. While the df=1d_{\rm f}=1 result of spheres (Renyi's classical car parking problem) can be derived analytically, evidence for the 1/df1/d_{\rm f} scaling for arbitrary particle shapes has so far only been provided from empirical studies on a case-by-case basis. Here, we show that the RSA of arbitrary non-spherical particles, whose centres of mass are constrained to fall on a line, can be solved analytically for moderate aspect ratios. The asymptotic jamming coverage is determined by a Laplace-type integral, whose asymptotics is fully specified by the contact distance between two particles of given orientations. The analysis of the contact function rr shows that the scaling exponent depends on particle shape and falls into two universality classes for generic shapes with d~\tilde{d} orientational degrees of freedom: (i) ν=1/(1+d~/2)\nu=1/(1+\tilde{d}/2) when rr is a smooth function of the orientations as for smooth convex shapes, e.g., ellipsoids; (ii) ν=1/(1+d~)\nu=1/(1+\tilde{d}) when rr contains singularities due to flat sides as for, e.g., spherocylinders and polyhedra. The exact solution explains in particular why many empirically observed scalings in 2d2d and 3d3d fall in between these two limiting values.

Keywords

Cite

@article{arxiv.1611.03034,
  title  = {Shape universality classes in the random sequential addition of non-spherical particles},
  author = {Adrian Baule},
  journal= {arXiv preprint arXiv:1611.03034},
  year   = {2017}
}

Comments

5 pages, 1 figure

R2 v1 2026-06-22T16:47:25.034Z