Possible superconductivity in $d^{n} (n\neq 9)$ platforms ?
Abstract
Superconductivity in square BX-plane-based materials currently is only found in configuration. This raises a question that whether other configurations () of transition metals in the prototype of square BX plane can also host superconductivity. We systematically explore this question via analyzing the electronic structure of materials from to platforms using density-functional calculation, including existing materials SrFeO and SrFeOF, and proposed ones LaNiOF and LaCoOF. Results show a good commonality between these materials and the cuprate and nickelate superconductors in their high-energy electronic structure, namely dominant low-energy states by ligand and orbitals. Other orbitals are all in the high-energy channel due to strong intra-atomic repulsion resulting in similar low-energy effective Hamiltonian except for the different number of local spins. These results hopefully suggest the possible superconductivity besides the prototype of . Superconducting phases found in these sets of materials will be highly valuable to understand the high-temperature superconductivity and even to find better superconducting families than the cuprates.
Cite
@article{arxiv.2304.01127,
title = {Possible superconductivity in $d^{n} (n\neq 9)$ platforms ?},
author = {Zi-Jian Lang},
journal= {arXiv preprint arXiv:2304.01127},
year = {2023}
}
Comments
11 pages