English

Possible superconductivity in $d^{n} (n\neq 9)$ platforms ?

Superconductivity 2023-04-04 v1

Abstract

Superconductivity in square BX2_2-plane-based materials currently is only found in d9d^9 configuration. This raises a question that whether other configurations dnd^{n} (n9n\neq 9) of transition metals in the prototype of square BX2_2 plane can also host superconductivity. We systematically explore this question via analyzing the electronic structure of materials from d8d^{8} to d5d^5 platforms using density-functional calculation, including existing materials SrFeO2_2 and SrFeO2_2F, and proposed ones LaNiO2_2F and LaCoO2_2F. Results show a good commonality between these materials and the cuprate and nickelate superconductors in their high-energy electronic structure, namely dominant low-energy states by ligand pp and dx2y2d_{x^2-y^2} orbitals. Other dd orbitals are all in the high-energy channel due to strong intra-atomic repulsion resulting in similar low-energy effective Hamiltonian except for the different number of local spins. These results hopefully suggest the possible superconductivity besides the prototype of d9d^9. Superconducting phases found in these sets of materials will be highly valuable to understand the high-temperature superconductivity and even to find better superconducting families than the cuprates.

Keywords

Cite

@article{arxiv.2304.01127,
  title  = {Possible superconductivity in $d^{n} (n\neq 9)$ platforms ?},
  author = {Zi-Jian Lang},
  journal= {arXiv preprint arXiv:2304.01127},
  year   = {2023}
}

Comments

11 pages

R2 v1 2026-06-28T09:47:10.991Z