Phase-Modulated Rapid-Scanning Fluorescence-Detected Two-Dimensional Electronic Spectroscopy
Optics
2021-09-15 v1 Other Condensed Matter
Chemical Physics
Abstract
We present a rapid-scanning approach to fluorescence-detected two-dimensional electronic spectroscopy that combines acousto-optic phase-modulation with digital lock-in detection. The approach shifts the signal detection window to suppress 1/f laser noise and enables interferometric tracking of the time delays to allow for correction of spectral phase distortions and accurate phasing of the data. This use of digital lock-in detection enables acquisition of linear and nonlinear signals of interest in a single measurement. We demonstrate the method on a laser dye, measuring the linear fluorescence excitation spectrum, as well as rephasing, non-rephasing and absorptive fluorescence-detected two-dimensional electronic spectra.
Cite
@article{arxiv.2105.13319,
title = {Phase-Modulated Rapid-Scanning Fluorescence-Detected Two-Dimensional Electronic Spectroscopy},
author = {Damianos Agathangelou and Ariba Javed and Francesco Sessa and Xavier Solinas and Manuel Joffre and Jennifer P. Ogilvie},
journal= {arXiv preprint arXiv:2105.13319},
year = {2021}
}