English

Multicomponent fluids of hard hyperspheres in odd dimensions

Soft Condensed Matter 2015-03-17 v2 Statistical Mechanics Chemical Physics

Abstract

Mixtures of hard hyperspheres in odd space dimensionalities are studied with an analytical approximation method. This technique is based on the so-called Rational Function Approximation and provides a procedure for evaluating equations of state, structure factors, radial distribution functions, and direct correlations functions of additive mixtures of hard hyperspheres with any number of components and in arbitrary odd-dimension space. The method gives the exact solution of the Ornstein--Zernike equation coupled with the Percus--Yevick closure, thus extending to arbitrary odd dimension the solution for hard-sphere mixtures [J. L. Lebowitz, Phys.\ Rev.\ \textbf{133}, 895 (1964)]. Explicit evaluations for binary mixtures in five dimensions are performed. The results are compared with computer simulations and a good agreement is found.

Keywords

Cite

@article{arxiv.1010.4120,
  title  = {Multicomponent fluids of hard hyperspheres in odd dimensions},
  author = {René D. Rohrmann and Andrés Santos},
  journal= {arXiv preprint arXiv:1010.4120},
  year   = {2015}
}

Comments

16 pages, 8 figures; v2: slight change of notation

R2 v1 2026-06-21T16:31:20.604Z