Depletion potential in the infinite dilution limit
Abstract
The depletion force and depletion potential between two in principle unequal "big" hard spheres embedded in a multicomponent mixture of "small" hard spheres are computed using the Rational Function Approximation method for the structural properties of hard-sphere mixtures [S. B. Yuste, A. Santos, and M. L\'opez de Haro, J. Chem. Phys. {\bf 108}, 3683 (1998)]. The cases of equal solute particles and of one big particle and a hard planar wall in a background monodisperse hard-sphere fluid are explicitly analyzed. An improvement over the performance of the Percus-Yevick theory and good agreement with available simulation results are found
Cite
@article{arxiv.0711.3633,
title = {Depletion potential in the infinite dilution limit},
author = {Santos Bravo Yuste and Andrés Santos and Mariano López de Haro},
journal= {arXiv preprint arXiv:0711.3633},
year = {2015}
}
Comments
10 pages, 5 figures; v2: few minor additions and reduction in the number of figures; v3: Fig. 2 corrected (see http://dx.doi.org/10.1063/1.4874639)