English

Marginally compact hyperbranched polymer trees

Soft Condensed Matter 2022-02-01 v1

Abstract

Assuming Gaussian chain statistics along the chain contour, we generate by means of a proper fractal generator hyperbranched polymer trees which are marginally compact. Static and dynamical properties, such as the radial intrachain pair density distribution or the shear-stress relaxation modulus, are investigated theoretically and by means of computer simulations. We emphasize that albeit the self-contact density diverges logarithmically with the total mass NN, this effect becomes rapidly irrelevant with increasing spacer length SS. In addition to this it is seen that the standard Rouse analysis must necessarily become inappropriate for compact objects for which the relaxation time τp\tau_p of mode pp must scale as τp(N/p)5/3\tau_p \sim (N/p)^{5/3} rather than the usual square power law for linear chains.

Keywords

Cite

@article{arxiv.2201.13141,
  title  = {Marginally compact hyperbranched polymer trees},
  author = {M. Dolgushev and J. P. Wittmer and A. Johner and O. Benzerara and H. Meyer and J. Baschnagel},
  journal= {arXiv preprint arXiv:2201.13141},
  year   = {2022}
}

Comments

14 pages, 11 figures

R2 v1 2026-06-24T09:10:28.856Z