English

Glassy dynamics in monodisperse hard ellipsoids

Soft Condensed Matter 2008-09-18 v3 Disordered Systems and Neural Networks

Abstract

We present evidence from computer simulations for glassy dynamics in suspensions of monodisperse hard ellipsoids. In equilibrium, almost spherical ellipsoids show a first order transition from an isotropic phase to a rotator phase. When overcompressing the isotropic phase into the rotator regime, we observe super-Arrhenius slowing down of diffusion and relaxation, accompanied by two-step relaxation in positional and orientational correlators. The effects are strong enough for asymptotic laws of mode-coupling theory to apply. Glassy dynamics are unusual in monodisperse systems. Typically, polydispersity in size or a mixture of particle species is prerequisite to prevent crystallization. Here, we show that a slight particle anisometry acts as a sufficient source of disorder. This sheds new light on the question of which ingredients are required for glass formation.

Keywords

Cite

@article{arxiv.0802.3124,
  title  = {Glassy dynamics in monodisperse hard ellipsoids},
  author = {Patrick Pfleiderer and Kristina Milinkovic and Tanja Schilling},
  journal= {arXiv preprint arXiv:0802.3124},
  year   = {2008}
}

Comments

included data of prolate system in all figures and text, extended discussion of indicators of glassy dynamics, fixed symbol ambiguities, preprint format

R2 v1 2026-06-21T10:14:42.189Z