Glassy dynamics in monodisperse hard ellipsoids
Abstract
We present evidence from computer simulations for glassy dynamics in suspensions of monodisperse hard ellipsoids. In equilibrium, almost spherical ellipsoids show a first order transition from an isotropic phase to a rotator phase. When overcompressing the isotropic phase into the rotator regime, we observe super-Arrhenius slowing down of diffusion and relaxation, accompanied by two-step relaxation in positional and orientational correlators. The effects are strong enough for asymptotic laws of mode-coupling theory to apply. Glassy dynamics are unusual in monodisperse systems. Typically, polydispersity in size or a mixture of particle species is prerequisite to prevent crystallization. Here, we show that a slight particle anisometry acts as a sufficient source of disorder. This sheds new light on the question of which ingredients are required for glass formation.
Keywords
Cite
@article{arxiv.0802.3124,
title = {Glassy dynamics in monodisperse hard ellipsoids},
author = {Patrick Pfleiderer and Kristina Milinkovic and Tanja Schilling},
journal= {arXiv preprint arXiv:0802.3124},
year = {2008}
}
Comments
included data of prolate system in all figures and text, extended discussion of indicators of glassy dynamics, fixed symbol ambiguities, preprint format