English

Describing screening in dense ionic fluids with a charge-frustrated Ising model

Soft Condensed Matter 2018-11-01 v2 Statistical Mechanics

Abstract

Charge correlations in dense ionic fluids give rise to novel effects such as long-range screening and colloidal stabilization which are not predicted by the classic Debye-Huckel theory. We show that a Coulomb or charge-frustrated Ising model, which accounts for both long-range Coulomb and short-range molecular interactions, simply describes some of these ionic correlations. In particular, we obtain at mean field level and in simulations, a non-monotonic dependence of the screening length on the temperature. Using a combination of simulations and mean field theories, we study how the correlations in the various regimes are affected by the strength of the short ranged interactions.

Keywords

Cite

@article{arxiv.1810.00918,
  title  = {Describing screening in dense ionic fluids with a charge-frustrated Ising model},
  author = {Nicholas B. Ludwig and Kinjal Dasbiswas and Dmitri V. Talapin and Suriyanarayanan Vaikuntanathan},
  journal= {arXiv preprint arXiv:1810.00918},
  year   = {2018}
}

Comments

8 pages, 6 figures

R2 v1 2026-06-23T04:24:56.427Z