Describing screening in dense ionic fluids with a charge-frustrated Ising model
Soft Condensed Matter
2018-11-01 v2 Statistical Mechanics
Abstract
Charge correlations in dense ionic fluids give rise to novel effects such as long-range screening and colloidal stabilization which are not predicted by the classic Debye-Huckel theory. We show that a Coulomb or charge-frustrated Ising model, which accounts for both long-range Coulomb and short-range molecular interactions, simply describes some of these ionic correlations. In particular, we obtain at mean field level and in simulations, a non-monotonic dependence of the screening length on the temperature. Using a combination of simulations and mean field theories, we study how the correlations in the various regimes are affected by the strength of the short ranged interactions.
Cite
@article{arxiv.1810.00918,
title = {Describing screening in dense ionic fluids with a charge-frustrated Ising model},
author = {Nicholas B. Ludwig and Kinjal Dasbiswas and Dmitri V. Talapin and Suriyanarayanan Vaikuntanathan},
journal= {arXiv preprint arXiv:1810.00918},
year = {2018}
}
Comments
8 pages, 6 figures