English

A minimizing principle for the Poisson-Boltzmann equation

Soft Condensed Matter 2013-01-14 v1 Statistical Mechanics Computational Physics

Abstract

The Poisson-Boltzmann equation is often presented via a variational formulation based on the electrostatic potential. However, the functional has the defect of being non-convex. It can not be used as a local minimization principle while coupled to other dynamic degrees of freedom. We formulate a convex dual functional which is numerically equivalent at its minimum and which is more suited to local optimization.

Keywords

Cite

@article{arxiv.1201.1415,
  title  = {A minimizing principle for the Poisson-Boltzmann equation},
  author = {A. C. Maggs},
  journal= {arXiv preprint arXiv:1201.1415},
  year   = {2013}
}

Comments

5 pages, 0 figures

R2 v1 2026-06-21T20:01:17.464Z