Related papers: ''Averaged'' statistical thermodynamics, energy eq…
The Nernst formulation of the third law of ordinary thermodynamics (often referred to as the ``Nernst theorem'') asserts that the entropy, $S$, of a system must go to zero (or a ``universal constant'') as its temperature, $T$, goes to zero.…
The first part of this paper is a condensed synthesis of the matter presented in several previous ones. It begins with an argumentation showing that the first and second laws of thermodynamics are incompatible with one another if they are…
The standard theory of ideal gases ignores the interaction of the gas particles with the thermal radiation (photon gas) that fills the otherwise vacuum space between them. This is an unphysical feature since every material absorbs and…
This research aims to introduce a new principle in the flat space-time geometry through the elimination of the classical idea of rest and by including a universal minimum limit of speed in the quantum world. This limit, unattainable by the…
We assume that markovian dynamics on a finite graph enjoys a gauge symmetry under local scalings of the probability density, derive the transformation law for the transition rates and interpret the thermodynamic force as a gauge potential.…
Generalization through novel interpretations of the inner logic of the century-old Gibbs' statistical thermodynamics is presented: i) Identifying $k_B\to 0$ as classical energetics, one directly derives a pair of thermodynamic variational…
With subrecoil-laser-cooled atoms one may reach nano-Kelvin temperatures while the ergodic properties of these systems do not follow usual statistical laws. Instead, due to an ingenious trapping mechanism in momentum space,…
It is sometimes argued that the unattainability of zero temperature is a consequence of the second law of thermodynamics. Historically, the independence of the unattainability of zero temperature from the second law was proven more than 80…
In this study, we present a reformulation of classical equilibrium thermodynamics by replacing the obscure and ambiguous concept of entropy with the clear and intuitive concept of information stored in a thermodynamic system. Specifically,…
People are well aware that, inherently, certain small-scale nonchaotic particle movements are not governed by thermodynamics. Usually, such phenomena are studied by kinetic theory and their energy properties are considered "trivial". In…
I argue here that both the first and second laws of thermodynamics, generally understood to be quintessentially physical in nature, can be equally well described as being about certain types of information without the need to invoke…
The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…
The generalized zeroth law of thermodynamics indicates that the physical temperature in nonextensive statistical mechanics is different from the inverse of the Lagrange multiplier, beta. This leads to modifications of some of thermodynamic…
The laws of thermodynamics provide a clear concept of the temperature for an equilibrium system in the continuum limit. Meanwhile, the equipartition theorem allows one to make a connection between the ensemble average of the kinetic energy…
We show an attempt to establish the zeroth law of thermodynamics within the framework of nonextensive statistical mechanics based on the classic normalization $\texttt{Tr}\hat{\rho}=1$ and the unnormalized expectation…
As no heat effect and mechanical work are observed, we have a simple experimental resolution of the Gibbs paradox: both the thermodynamic entropy of mixing and the Gibbs free energy change are zero during the formation of any ideal…
The purpose of this note is to see to what extent ideal gas laws can be obtained from simple Newtonian mechanics, specifically elastic collisions. We present simple one-dimensional situations that seem to validate the laws. The first…
The quantum statistical mechanics of an ideal gas with a general free-particle energy obeying fractional exclusion statistics are systematically investigated in arbitrary dimensions. The pressure relations, the relation between pressure and…
In textbooks on statistical mechanics, one finds often arguments based on classical mechanics, phase space and ergodicity in order to justify the second law of thermodynamics. However, the basic equations of motion of classical mechanics…
It has long been taken for granted that there is only one type of thermodynamic system near absolute zero temperature: the ordinary one compatible with all statements of the third law, with a fundamental yet tacit assumption that all heat…