Related papers: ''Averaged'' statistical thermodynamics, energy eq…
The equations of state for an ideal generalized gas, like an ideal quantum gas, are expressed in terms of power laws of the temperature. The reduction of an ideal generalized gas to an ideal classical case occurs when the characteristic…
The Principle of Unattainability rules out the attainment of absolute zero temperature by any finite physical means, no matter how idealised they could be. Nevertheless, we clarify that the Third Law of Thermodynamics, as defined by…
In statistical mechanics the zeroth law of thermodynamics is taken as a postulate which, as its name indicates, logically precedes the first and second laws. Treating it as a postulate has consequences for how temperature is introduced into…
The formulas for the entropy of ideal gases mixture and the entropy change in mixing of ideal gases on the basis of the third law of thermodynamics were obtained. It is shown that when using these formulas, the Gibbs paradox within the…
This article describes the third law of thermodynamics. This law is often poorly known and is often decried, or even considered optional and irrelevant to describe weather and climate phenomena. This, however, is inaccurate and contrary to…
The third law of thermodynamics in the form of the unattainability principle states that exact ground-state cooling requires infinite resources. Here we investigate the amount of non-equilibrium resources needed for approximate cooling. We…
The third law of thermodynamics has a controversial past and a number of formulations due to Planck, Einstein, and Nernst. It's most accepted version, the unattainability principle, states that "any thermodynamic process cannot reach the…
There would be a perfect correspondence between the laws of classical thermodynamics and black hole thermodynamics, except for the apparent failure of black hole thermodynamics to correspond to the Third Law. The classical Third Law of…
We investigate thermodynamics of general nonequilibrium processes stopped at stochastic times. We propose a systematic strategy for constructing fluctuation-theorem-like martingales for each thermodynamic functional, yielding a family of…
This work consists in the theorical development on the analysis of the Thermodynamic Laws and thermodynamic systems in relative motion, according to the laws of Classical Mechanics. The difference of this work for many of the literature is…
The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy…
We show that when the thermal wavelength is comparable to the spatial size of a system, thermodynamic observables like Pressure and Volume have quantum fluctuations that cannot be ignored. They are now represented by operators; conventional…
A classical particle system coupled with a thermostat driven by an external constant force reaches its steady state when the ensemble-averaged drift velocity does not vary with time. The statistical mechanics of such a system is derived…
The physical impossibility of heat transfer under isothermal conditions implies that the classical expression for the entropy of the ideal gas may not be compatible with the internal energy of the gas itself. A corrected expression of the…
We propose a fundamental relation for a classical ideal gas that is valid at all temperatures with remarkable accuracy. All thermodynamical properties of classical ideal gases can be deduced from this relation at arbitrary temperature.
Using a game theory approach and a new extremal problem, Gibbs formula is proved in a most simple and general way for the classical mechanics case. A corresponding conjecture on the asymptotics of the classical entropy is formulated. For…
We present here an exploration on on the physical implications of the Darwinian dynamics. We first show that how the nonequilibrium statistical mechanics emerges naturally. We then show that the first three laws of the thermodynamics, the…
It is presented a microscopic interpretation for the temperature within Tsallis thermostatistics, generalizing the classical derivation based on the Boltzmann-Gibbs statistics. It is shown that with this definition the zeroth law and the…
We consider a heavy external object moving in an ideal gas of light particles. Collisions with the gas particles transfer momentum to the object, leading to a force that is proportional to the object's velocity but in the opposite…
The zeroth principle of thermodynamics in the form "temperature is uniform at equilibrium" is notoriously violated in relativistic gravity. Temperature uniformity is often derived from the maximization of the total number of microstates of…