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We generalize the second law of thermodynamics in its maximum work formulation for a nonequilibrium initial distribution. It is found that in an isothermal process, the Boltzmann relative entropy (H-function) is not just a Lyapunov function…

Statistical Mechanics · Physics 2015-05-13 H. -H. Hasegawa , J. Ishikawa , K. Takara , D. J. Driebe

The second law of thermodynamics dictates that heat flows spontaneously from a high-temperature entity to a lower-temperature one. Yet, recent advances have demonstrated that quantum correlations between a system and its thermal environment…

We consider a class of quantum heat engines consisting of two subsystems interacting via a unitary transformation and coupled to two separate baths at different temperatures $T_h > T_c$. The purpose of the engine is to extract work due to…

Statistical Mechanics · Physics 2009-11-13 Armen E. Allahverdyan , Ramandeep S. Johal , Guenter Mahler

Using the quasi-equilibrium Helmholtz energy (qHE), defined as the thermodynamic work in a quasi-static process, we investigate the thermal properties of both an isothermal process and a transition process between the adiabatic and…

Statistical Mechanics · Physics 2022-07-06 Shoki Koyanagi , Yoshitaka Tanimura

After presenting possible motives for fighting against the second law of thermodynamics, several attempts to beat this law are analyzed. The second law wins, but an interesting interpretation of it emerges. This interpretation uses the…

adap-org · Physics 2015-06-30 Jorge Berger

We introduce a family of Maxwellian Demons for which correlations among information bearing degrees of freedom can be calculated exactly and in compact analytical form. This allows one to precisely determine Demon functional thermodynamic…

Statistical Mechanics · Physics 2016-03-23 A. B. Boyd , D. Mandal , J. P. Crutchfield

Local master equations are a widespread tool to model open quantum systems, especially in the context of many-body systems. These equations, however, are believed to lead to thermodynamic anomalies and violation of the laws of…

Quantum Physics · Physics 2021-02-23 Adam Hewgill , Gabriele De Chiara , Alberto Imparato

The second law of thermodynamics dictates the fundamental limits to the amount of energy and information that can be exchanged between physical systems. In this work, we extend a thermodynamic formalism describing this flow of energy and…

Statistical Mechanics · Physics 2015-03-24 Jordan M. Horowitz

Statistical mechanics descriptions of the second law of thermodynamics generally imply point-like particles driven by a dissipative overall mechanism for their simultaneous time-evolution. As the number of involved particles grows larger,…

General Physics · Physics 2016-02-16 Hans R. Moser

Thermodynamic cycles are idealized processes that can convert heat into work or produce heat flow against a temperature gradient with the input of work. They remain an active area of research in modern stochastic thermodynamics. In…

Statistical Mechanics · Physics 2026-02-12 S. Liu , A. Datta , A. C. Barato

Events in mesoscopic systems often take place at first-passage times, as is for instance the case for a colloidal particle that escapes a metastable state. An interesting question is how much work an external agent has done on a particle…

Statistical Mechanics · Physics 2020-02-05 Izaak Neri

We investigate the connection between recent results in quantum thermodynamics and fluctuation relations by adopting a fully quantum mechanical description of thermodynamics. By including a work system whose energy is allowed to fluctuate,…

Quantum Physics · Physics 2017-03-27 Álvaro M. Alhambra , Lluis Masanes , Jonathan Oppenheim , Christopher Perry

A tantalizing version of Maxwell's demon is presented which appears to operate reversibly. A container of hard core disks is separated into two chambers of equal volume by a membrane that selects which disk can penetrate depending on the…

chao-dyn · Physics 2009-10-22 P. A. Skordos

We study the modification of the second law of thermodynamics for a quantum system interacting with a reservoir regarding quantum coherence. The whole system is isolated so that neither energy nor information is lost. It is discovered that…

Quantum Physics · Physics 2021-10-12 Yu-Han Ma , C. L. Liu , C. P. Sun

Assigning the variations of internal energy into heat or work contributions is a challenging task due to the fact that these properties are trajectory dependent. A number of proposals have been put forward for open quantum systems following…

Quantum Physics · Physics 2021-09-01 Adrián Juan-Delgado , Aurélia Chenu

Engines are systems and devices that convert one form of energy into another, typically into a more useful form that can perform work. In the classical setup, physical, chemical, and biological engines largely involve the conversion of heat…

Quantum Physics · Physics 2024-11-19 Loris Maria Cangemi , Chitrak Bhadra , Amikam Levy

The second law of equilibrium thermodynamics explains the direction of spontaneous processes in a system after removing internal constraints. When the system only exchanges energy with the environment as heat, the second law states that…

Statistical Mechanics · Physics 2024-04-30 Robert Hołyst , Paweł Jan Żuk , Anna Maciołek , Karol Makuch , Konrad Giżyński

We propose a new form of the Second Law inequality that defines a tight bound for extractable work from the non-equilibrium quantum state. In classical thermodynamics, the optimal work is given by the difference of free energy, what…

Quantum Physics · Physics 2023-02-14 Marcin Łobejko

We address the question of verifying the quantumness of thermal machines. A Szil\'ard engine is truly quantum if its work output cannot be described by a local hidden state (LHS) model, i. e. an objective local statistical ensemble.…

Quantum Physics · Physics 2019-12-25 Konstantin Beyer , Kimmo Luoma , Walter T. Strunz

Recently Allahverdyan and Nieuwenhuizen (cond-mat/0006404) argued that the second law of thermodynamics may be violated in a quantum system as a "consequence of quantum coherence in the presence of the slightly off-equilibrium nature of the…

Statistical Mechanics · Physics 2007-05-23 Hal Tasaki
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