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A new scheme for enantiomer differentiation of chiral molecules using a pair of linearly polarized intense ultrashort laser pulses with skewed mutual polarization is presented. The technique relies on the fact that the off-diagonal…

Chemical Physics · Physics 2017-05-04 Andrey Yachmenev , Sergei N. Yurchenko

Understanding and controlling the electronic as well as ro-vibrational motion and, thus, the entire chemical dynamics in molecules is the ultimate goal of ultrafast laser and imaging science. In photochemistry, laser-induced dissociation…

We present a theoretical framework for electromagnetic scattering by particles with a permittivity that is periodically varying in time, based on a perturbative approach. Within this framework, we derive explicit expressions for the…

The time-dependent optical properties of molecular systems are investigated by step-scan Fourier-transform spectroscopy in order to explore the dynamics at phase transitions and molecular orientation in the milli- and microsecond range. The…

Materials Science · Physics 2016-07-20 Tobias Peterseim , Martin Dressel

By using perturbation theory we derive an expression for the electrical field of a Gaussian laser pulse propagating in a gas medium. This expression is used as a trial solution in a variational method to get quasianalytical solutions for…

Optics · Physics 2009-11-11 E. Arevalo , A. Becker

Intense and energetic electron currents can be generated by ultra-intense lasers interacting with solid density targets. Especially for ultra-short laser pulses their temporal evolution needs to be taken into account for many non-linear…

Plasma Physics · Physics 2019-01-02 Thomas Kluge , Michael Bussmann , Thomas E. Cowan , Ulrich Schramm

We propose a theoretical and computational approach to investigate temporal behavior of a nonlinear polarization in perturbative regime induced by an intense and ultrashort pulsed electric field. First-principles time-dependent density…

Optics · Physics 2019-03-27 Mitsuharu Uemoto , Yuki Kuwabara , Shunsuke A. Sato , Kazuhiro Yabana

We show, both classically and quantum mechanically, enantioselective orientation of gas phase chiral molecules excited by laser fields with twisted polarization. Counterintuitively, the induced orientation, whose direction is laser…

Chemical Physics · Physics 2019-10-16 Ilia Tutunnikov , Johannes Floß , Erez Gershnabel , Paul Brumer , Ilya Sh. Averbukh

Since its invention in 1999, optical centrifuge has become a powerful tool for controlling molecular rotation and studying molecular dynamics and molecular properties at extreme levels of rotational excitation. The technique has been…

Instrumentation and Detectors · Physics 2020-05-20 Ian MacPhail-Bartley , Walter W. Wasserman , Alexander A. Milner , V. Milner

The transition between two distinct mechanisms for the laser-induced field-free orientation of CO molecules is observed via measurements of orientation revival times and subsequent comparison to theoretical calculations. In the first…

We examine x-ray scattering from an isolated organic molecule from the linear to nonlinear absorptiveregime. In the nonlinear regime, we explore the importance of both the elastic and inelastic channelsand observe the onset of nonlinear…

Chemical Physics · Physics 2021-06-09 Phay J. Ho , Adam E. A. Fouda , Kai Li , Gilles Doumy , Linda Young

The ultrafast time-dependence of the energy absorption of covalent solids upon excitation with femtosecond laser pulses is theoretically analyzed. We use a microscopic theory to describe laser induced structural changes and their influence…

Materials Science · Physics 2007-05-23 H. O. Jeschke , M. E. Garcia , K. H. Bennemann

Our exact theory for continuous harmonic perturbation of a one dimensional model atom by parametric variations of its potential is generalized for the cases when a) the atom is exposed to short pulses of an external harmonic electric field…

Atomic and Molecular Clusters · Physics 2016-11-03 Alexander Rokhlenko

The generation of ultrashort pulses hinges on the careful management of dispersion. Traditionally, this has exclusively involved second-order dispersion, while higher-order dispersion was treated as a nuisance to be minimized. Here we show…

The infinite-dimensional Hubbard model is studied by means of a modified perturbation theory. The approach reduces to the iterative perturbation theory for weak coupling. It is exact in the atomic limit and correctly reproduces the…

Strongly Correlated Electrons · Physics 2009-10-30 T. Wegner , M. Potthoff , W. Nolting

Laser ablation is often explained by a two-temperature model (TTM) with different electron and lattice temperatures. To realize a classical molecular dynamics simulation of the TTM, we propose an extension of the embedded atom method to…

Materials Science · Physics 2022-03-09 Yuta Tanaka , Shinji Tsuneyuki

Thermodynamic perturbation theory is employed to derive analytical expressions for the equilibrium linear susceptibility and specific heat of lattices of anisotropic classical spins weakly coupled by the dipole-dipole interaction. The…

Materials Science · Physics 2009-11-07 P. E. Jönsson , J. L. Garcia-Palacios

Orientation states of two coupled polar molecules controlled by laser pulses are studied theoretically. By varying the period of a series of periodically applied laser pulse, transition from regular to chaotic behavior may occur. Schmidt…

Quantum Physics · Physics 2007-05-23 Ying-Yen Liao , Yueh-Nan Chen , Der-San Chuu

We investigate the photoelectron angular emission distributions obtained by strong field dissociative ionization of H$_2$ using cold target recoil ion momentum spectroscopy. In case of employing laser light with an ellipticity close to 0.9…

Ultrafast vectorially polarized pulses have found many applications in information and energy transfer owing mainly to the presence of strong longitudinal components and their space-polarization non-separability. Due to their broad…