Related papers: Electron attachment to valence-excited CO
Motivated by the huge need of data for non-equilibrium plasma modeling, a theoretical investigation of dissociative electron attachment to the NO molecule is performed. The calculations presented here are based on the…
We theoretically examine the effect of the coupling of the transport electrons to a vibrational mode of the molecule on the ac linear-response conductance of molecular junctions. Representing the molecule by a single electronic state, we…
Momentum imaging measurements from two experiments are presented and interpreted with the aid of new ab initio theoretical calculations to describe the dissociative electron attachment (DEA) dynamics. We address the problem of how the 4 eV…
Calculations are presented which use the molecular R-matrix with pseudo-states (MRMPS) method to treat electron impact electron detachment and electronic excitation of the carbon dimer anion. Resonances are found above the ionisation…
The intercombination $a^3\Pi - X^1\Sigma^+$ Cameron system of carbon monoxide has been computationally studied in the framework of multi-reference Fock space coupled cluster method with the use of generalized relativistic pseudopotential…
Coherent electrons coupled to the quantized electromagnetic field undergo decoherence which can be viewed as due either to fluctuations of the Aharonov-Bohm phase or to photon emission. When the electromagnetic field is in a squeezed vacuum…
We study the collective excitation of a gas of highly excited atoms confined to a large spacing ring lattice, where the ground and the excited states are coupled resonantly via a laser field. Our attention is focused on the regime where the…
We make a multipole expansion of the atomic/molecular electrostatic charge distribution as seen by the valence electron up to the quadrupole term. The Tridiagonal Representation Approach (TRA) is used to obtain an exact bound state solution…
A heavy-mass electron state is realized in a doped valence bond solid (Ti1-xVx)2O3. In this system, itinerant holes mediate the mainly ferromagnetic RKKY interaction between the localized magnetic moments and become readily spin-polarized…
The strongly coupled electron liquid provides a unique opportunity to study the complex interplay of strong coupling with quantum degeneracy effects and thermal excitations. To this end, we carry out extensive \textit{ab initio} path…
A systematic method to account for electron correlation in periodic systems which can predict quantitatively correct band structures of non-conducting solids from first principles is presented. Using localized Hartree-Fock orbitals (both…
The collisional coupling of relativistic electrons and non-relativistic ions in hot plasmas has been analysed. It is found that relativistic effects produce a new feature: while the condition T_e<3T_i guarantees a stable collisional…
We present experimental observations of seven vibrational levels $v'=20-26$ of the $1^{3}\Sigma_{g}^{+}$ excited state of Li$_2$ molecules by the photoassociation (PA) of a degenerate Fermi gas of $^6$Li atoms. For each vibrational level,…
We theoretically study the effect of electron-electron interactions in one-dimensional partially mixed helical states. These helical states can be realized at the edges of two-dimensional topological insulators with partially broken…
Dynamical Coherent-Potential Approximation (CPA) to correlated electrons has been extended to a system with realistic Hamiltonian which consists of the first-principles tight-binding Linear Muffintin Orbital (LMTO) bands and intraatomic…
We review the binding and energy level alignment of $\pi$-conjugated systems on metals, a field which during the last two decades has seen tremendous progress both in terms of experimental characterization as well as in the depth of…
We have observed short-range photoassociation of LiRb to the two lowest vibrational states of the $d\,^3\Pi$ potential. These $d\,^3\Pi$ molecules then spontaneously decay to vibrational levels of the $a^3\,\Sigma^+$ state with generation…
The Resonating Valence Bond theory of the chemical bond was introduced soon after the discovery of quantum mechanics and has contributed to explain the role of electron correlation within a particularly simple and intuitive approach where…
We study a simple electron-phonon model on square and triangular versions of the Lieb-lattice using an asymptotically exact strong coupling analysis. At zero temperature and electron density $n = 1$ (one electron per unit cell), for various…
Vibrational-excitation cross sections of ground electronic state of carbon dioxide molecule by electron-impact through the CO2-(2\Pi) shape resonance is considered in the separation of the normal modes approximation. Resonance curves and…