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Nitrous oxide is a long-lived greenhouse gas. Its isotopic composition provides valuable insights into sources and sinks, and about the mechanism of formation. A major challenge in the spectroscopic analysis of the isotopocule compositions…

Chemical Physics · Physics 2025-06-17 Adrian Hjältén , Ibrahim Sadiek , Aleksandra Foltynowicz

Accurate atomic transition data are important in many astronomical research areas especially in line spectroscopy study. Whereas transition data of He-like and H-like ions (i.e., ions at high-charge states) are accurately calculated, that…

High Energy Astrophysical Phenomena · Physics 2013-11-04 Jin-Yuan Liao , Shuang-Nan Zhang , Yangsen Yao

Intracavity laser absorption spectroscopy (ICLAS) with an evacuated Cr2+: ZnSe laser is performed with a high-resolution time-resolved Fourier transform interferometer with a minimum detectable absorption coefficient equal to 4 10-9 cm-1…

We have used a highly sensitive cavity-enhanced frequency modulation spectroscopy technique to measure different parameters of the ultraweak transitions of a${^1}{\triangle}_g{\leftarrow}$X $^3{\Sigma}^{-}_g$ $(0,0)$ band of molecular…

Optics · Physics 2013-04-23 Dipankar Das

\ Nitrous oxide (N$_2$O) ice is likely to exist in trans-Neptunian objects such as Pluto and Triton, potentially formed through ultraviolet (UV) radiation from the Sun or cosmic ray irradiation of N$_2$ and CO ices. However, the…

Earth and Planetary Astrophysics · Physics 2025-04-04 Daiki Takama , Ryoichi Koga , Shohei Negishi , Biao Zhao , Yuan Li , Yasuhiro Hirahara , Fumiyuki Ito

A tunable far-infrared laser sideband spectrometer was used to investigate a nitric oxide sample enriched in 18O between 0.99 and 4.75 THz. Regular, electric dipole transitions were recorded between 0.99 and 2.52 THz, while magnetic dipole…

Astrophysics of Galaxies · Physics 2015-04-21 Holger S. P. Müller , Kaori Kobayashi , Kazumasa Takahashi , Kazuko Tomaru , Fusakazu Matsushima

We developed a mid-infrared optical frequency comb-based Fourier-transform spectrometer and performed a line-shape study of the fundamental vibrational band of CO perturbed by N${_2}$, which is crucial for atmospheric science and…

Using a mid-infrared quantum cascade laser and wavelength modulation absorption spectroscopy, we measure the frequencies of ro-vibrational transitions of N$_2$O in the 17 $\mu$m region with uncertainties below 5 MHz. These lines,…

Atomic Physics · Physics 2025-12-10 Y. Wang , J. Rodewald , O. Lopez , M. Manceau , B. Darquié , B. E. Sauer , M. R. Tarbutt

We use an airborne pulsed integrated path differential absorption lidar to make spectroscopic measurements of the pressure-induced line broadening and line center shift of atmospheric CO2 at the 1572.335 nm absorption line. We measure the…

Precise molecular transition frequencies are of great interest in the test of fundamental physics and also in various applications. Two well isolated ro-vibrational transitions of $^{12}$C$^{16}$O at 1.57 $\mu$m, R(9) and R(10) in the…

Atomic Physics · Physics 2017-10-11 Jin Wang , Yu R. Sun , Lei-Gang Tao , An-Wen Liu , Shui-Ming Hu

Atmospheric carbon dioxide concentrations are being closely monitored by remote sensing experiments which rely on knowing line intensities with an uncertainty of 0.5% or better. We report a theoretical study providing rotation-vibration…

The $\lambda$ = 2.06 $\mu$m absorption band of CO$_2$ is widely used for the remote sensing of atmospheric carbon dioxide, making it relevant to many important top-down measurements of carbon flux. The forward models used in the retrieval…

Atomic Physics · Physics 2020-06-09 Hélène Fleurbaey , Hongming Yi , Erin M. Adkins , Adam J. Fleisher , Joseph T. Hodges

Accurate Fourier-transform spectroscopic absorption measurements of vacuum ultraviolet transitions in atomic nitrogen and carbon were performed at the Soleil synchrotron. For $^{14}$N transitions from the $2s^22p^3\,^4$S$_{3/2}$ ground…

Atomic Physics · Physics 2020-09-04 K. -F. Lai , W. Ubachs , N. de Oliveira , E. J. Salumbides

Using the Tunable Diode Laser Absorption Spectroscopy (TDLAS) 82 CH$_3$I ro-vibrational overtone absorption were detected for the first time between 11660 and 11840 cm$^{-1}$ (844 -- 857 nm), with strengths estimated to be around $10^{-27}$…

Chemical Physics · Physics 2023-04-14 Alessandro Lucchesini

Electron energy-loss spectrometry was employed to measure the white lines at the L23 absorption edges of the 3d transition-metal oxides and lithium transition-metal oxides. The white-line ratio (L3/L2) was found to increase between d^0 and…

Materials Science · Physics 2009-11-10 J. Graetz , C. C. Ahn , H. Ouyang , P. Rez , B. Fultz

The spectral dynamics of a mid-infrared multimode Cr^2+:ZnSe laser located in a vacuum sealed chamber containing acetylene at low pressure is analyzed by a stepping-mode high-resolution time-resolved Fourier transform interferometer.…

Spectra comprised of hundreds of time-components for absorption path lengths up to 130 km have been recorded around 1050 nm by combining two recent techniques, intracavity laser spectroscopy with vertical external cavity surface emitting…

Optics · Physics 2009-11-13 Nathalie Picqué , Guy Guelachvili , Alexander A. Kachanov

Quasar spectra reveal a rich array of important astrophysical information about galaxies which intersect the quasar line of sight. They also enable tests of the variability of fundamental constants over cosmological time and…

Cosmology and Nongalactic Astrophysics · Physics 2015-06-17 Michael T. Murphy , Julian C. Berengut

The frequencies and line strengths of the 2Pi3/2 J=5/2-3/2 rotational transition of 17OH have been calculated from an analysis of its far-infrared laser magnetic resonance spectrum. These results have been used to make the first detection…

Astrophysics · Physics 2009-11-10 E. T. Polehampton , J. M. Brown , B. M. Swinyard , J. -P. Baluteau

The atomic spectra and structure of the open d- and f-shell elements are extremely complex, where tens of thousands of transitions between fine structure energy levels can be observed as spectral lines across the infrared and UV per…

Atomic Physics · Physics 2025-01-23 M. Ding , S. Z. J. Lim , X. Yu , C. P. Clear , J. C. Pickering
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