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Supersonic beams of polar molecules are deflected using inhomogeneous electric fields. The quantum-state selectivity of the deflection is used to spatially separate molecules according to their quantum state. A detailed analysis of the…

We provide a theory of the deflection of polar and non-polar rotating molecules by inhomogeneous static electric field. Rainbow-like features in the angular distribution of the scattered molecules are analyzed in detail. Furthermore, we…

Chemical Physics · Physics 2015-05-20 E. Gershnabel , I. Sh. Averbukh

Electric deflection measurements on liquid helium nanodroplets doped with individual polar molecules demonstrate that the cold superfluid matrix enables full orientation of the molecular dipole along the external field. This translates into…

Atomic and Molecular Clusters · Physics 2016-11-21 Daniel J. Merthe , Vitaly V. Kresin

Helium nanodroplets doped with polar molecules are studied by electrostatic deflection. This broadly applicable method allows even polyatomic molecules to attain sub-Kelvin temperatures and nearly full orientation in the field. The…

Atomic and Molecular Clusters · Physics 2019-07-26 John W. Niman , Benjamin S. Kamerin , Daniel J. Merthe , Lorenz Kranabetter , Vitaly V. Kresin

The unsteady electrorotation of a drop of a viscous weakly conducting polarizable liquid suspended in another viscous weakly conducting polarizable liquid immiscible with the former in an applied constant uniform electric field is…

Fluid Dynamics · Physics 2017-10-11 Alexander N. Tyatyushkin

The manipulation of the motion of neutral molecules with electric or magnetic fields has seen tremendous progress over the last decade. Recently, these techniques have been extended to the manipulation of large and complex molecules. In…

Chemical Physics · Physics 2011-04-07 Frank Filsinger , Gerard Meijer , Henrik Stapelfeldt , Henry N. Chapman , Jochen Küpper

An electrostatic hexapole lens is used to manipulate the transverse properties of a beam of barium fluoride molecules from a cryogenic buffer gas source. The spatial distribution of the beam is measured by recording state-selective…

We consider deflection of rotating symmetric molecules by inhomogeneous optical and static electric fields, compare results with the case of linear molecules, and find new singularities in the distribution of the scattering angle.…

Chemical Physics · Physics 2015-05-28 Erez Gershnabel , Ilya Sh. Averbukh

We have developed and experimentally demonstrated an improved electrostatic deflector for the spatial separation of molecules according to their dipole-moment-to-mass ratio. The device features a very open structure that allows for…

Chemical Physics · Physics 2017-07-25 Jens S. Kienitz , Karol Długołecki , Sebastian Trippel , Jochen Küpper

A beam of rotating dipolar particles (molecules or clusters) will broaden when passed through an electric or magnetic field gradient region. This broadening, which is a common experimental observable, can be expressed in terms of the…

Atomic and Molecular Clusters · Physics 2012-01-05 Jaap Bulthuis , Vitaly V. Kresin

In this experiment liquid water is subject to an inhomogeneous electric field (${\nabla}^2 E_a {\approx} 10^{10} \frac{V}{m^2}$ ) using a high voltage (20 kV) point-plane electrode system. With interferometry it was found that the…

Mesoscale and Nanoscale Physics · Physics 2016-06-29 Adam D. Wexler , Sandra Drusová , Jakob Woisetschläger , Elmar C. Fuchs

A new mechanism is described, analyzed and visualized, for the dissipation of suprathermal rotation energy of molecules in magnetic fields, a necessary condition for their alignment. It relies upon the Lorentz force perturbing the motion of…

Astrophysics of Galaxies · Physics 2016-02-17 Renaud Papoular

Beam deflection is capable of providing valuable information about the magnetic moments of molecules and clusters as well as the relaxation dynamics of their spins. However, observations have been hampered by magnetic couplings to excited…

Atomic and Molecular Clusters · Physics 2025-08-13 Benjamin S. Kamerin , Thomas H. Villers , John W. Niman , Jiahao Liang , Angel I. Pena Dominguez , Vitaly V. Kresin

In this work, we put forward a theoretical explanation of a peculiar effect found very recently (A. Gonzalez Urena et al., Chem. Phys. Lett. 341 (2001) 495). They have observed the deflection of a beam of molecules posessing a permanent…

Chemical Physics · Physics 2007-05-23 M. Dorado , M. Morales Furio , J. L. Perez , J. L. Sanchez Gomez

We use two-dimensional transverse laser cooling to produce an ultracold beam of YbF molecules. Through experiments and numerical simulations, we study how the cooling is influenced by the polarization configuration, laser intensity, laser…

We study water between parallel metal walls under applied electric field accounting for the image effect at $T=298$ K. The electric field due to the surface charges serves to attract and orient nearby water molecules, while it tends to a…

Soft Condensed Matter · Physics 2015-07-24 Kyohei Takae , Akira Onuki

We report the creation of a confined slow beam of heavy-water (D2O) molecules with a translational temperature around 1 kelvin. This is achieved by filtering slow D2O from a thermal ensemble with inhomogeneous static electric fields…

Chemical Physics · Physics 2009-11-11 T. Rieger , T. Junglen , S. A. Rangwala , G. Rempe , P. W. H. Pinkse , J. Bulthuis

Heavy polar molecules can be used to measure the electric dipole moment of the electron, which is a sensitive probe of physics beyond the Standard Model. The value is determined by measuring the precession of the molecule's spin in a plane…

Atomic Physics · Physics 2010-01-29 M. R. Tarbutt , J. J. Hudson , B. E. Sauer , E. A. Hinds

An investigation on stochastic deflection of high-energy charged particles in a bent crystal was carried out. In particular, we investigated the deflection efficiency under axial confinement of both positively and negatively charged…

In conventional optical Stark-shift spectroscopy, molecules are exposed to spatially homogeneous static electric fields that shift the energies of their spectral lines. These shifts are attributed to the molecular electronic properties,…

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