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An analytical representation for the potential energy curve for the ground state $X^1\Sigma^+$ of the hydrogen fluoride molecule (HF) is presented in the frame of the Born-Oppenheimer approximation. The analytical expression for the…

Chemical Physics · Physics 2021-10-29 Laura E. Angeles Gantes , Horacio Olivares-Pilón

The metastable a(1)[^3\Sigma^+] state of PbO has been suggested as a suitable system in which to search for the electric dipole moment (EDM) of the electron. We report here the development of experimental techniques allowing…

High Energy Physics - Experiment · Physics 2009-11-10 D. Kawall , F. Bay , S. Bickman , Y. Jiang , D. DeMille

Excluding the very shallow potential minimum of the electronic ground state, all bound electronic states of He$_2$ have Rydberg character. Their potential-energy functions are similar to those of the He$_2^+$ states to which the Rydberg…

Atomic Physics · Physics 2025-08-12 M. Holdener , V. Wirth , N. A. Shahin , M. Beyer , F. Merkt

The electronic structure of Samarium (Sm) was calculated using the density functional theory combined with the single-site dynamical mean-field theory. In this work, we investigated the electronic properties of {\alpha}, \b{eta} and…

Strongly Correlated Electrons · Physics 2026-05-15 Shengsong Xu , Zhenfeng Ouyang , Li Huang , Zhong-Yi Lu

We report an investigation of the low-lying excited states of the YbF molecule--a candidate molecule for experimental measurements of the electron electric dipole moment--with 2-component based multi-reference configuration interaction…

Chemical Physics · Physics 2023-09-18 Johann V. Pototschnig , Kenneth G. Dyall , Lucas Visscher , André S. P. Gomes

HfF$^+$ cation is a very promising system to search for the electron electric dipole moment (EDM), and corresponding experiment is carried out by E. Cornell group. Here we theoretically investigate the cation to search for another T,P-odd…

Atomic Physics · Physics 2017-03-08 L. V. Skripnikov , A. V. Titov , V. V. Flambaum

We present a first principles strategy for developing state-specific density functional approximations for excited states. We first clarify why approaches based on conventional ground state approximations miss density-driven correlations,…

Chemical Physics · Physics 2025-06-09 Tim Gould , Stephen G Dale , Leeor Kronik , Stefano Pittalis

Matching for a wavefunction the WKB expansion at large distances and Taylor expansion at small distances leads to a compact, few-parametric uniform approximation found in {\it J. Phys. B44, 101002 (2011)}. The ten low-lying eigenstates of…

Quantum Physics · Physics 2019-08-13 Horacio Olivares-Pilón , Alexander V. Turbiner

The NL-$e$EDM experiment searches for a non-zero electric dipole moment of the electron $d_e$ ($e$EDM) in the ground state of barium monofluoride (BaF). A beam of BaF from a supersonic expansion source is probed with the spin precession…

We report calculation of the energy spectrum and the spectroscopic properties of the superheavy element ion: Rf^+. We use the 4-component relativistic Dirac-Coulomb Hamiltonian and the multireference configuration interaction (MRCI) model…

Atomic Physics · Physics 2021-08-24 Harry Ramanantoanina , Anastasia Borschevsky , Michael Block , Mustapha Laatiaoui

When a three-dimensional electron gas is subjected to a very strong magnetic field, it can reach a quasi-one-dimensional state in which all electrons occupy the lowest Landau level. This state is referred to as the extreme quantum limit…

Mesoscale and Nanoscale Physics · Physics 2017-04-05 M. Sammon , Han Fu , B. I. Shklovskii

We discuss the role of dynamical many-electron effects in the physics of iron and iron-rich solid alloys under applied pressure on the basis of recent ab initio studies employing the dynamical mean-field theory (DMFT). Electronic…

Strongly Correlated Electrons · Physics 2019-09-19 Leonid V. Pourovskii

Electric dipole ($E1$) response of $^{6}$He is studied with a fully microscopic six-body calculation. The wave functions for the ground and excited states are expressed as a superposition of explicitly correlated Gaussians (CG). Final state…

Nuclear Theory · Physics 2015-06-19 D. Mikami , W. Horiuchi , Y. Suzuki

Theoretical analysis of the experimental data for the energy levels of two interacting electrons confined by a finite Gaussian potential in a 2D quantum dot and subjected to a uniform magnetic field perpendicular to the plane of the dot is…

Mesoscale and Nanoscale Physics · Physics 2022-07-27 S. Chaudhuri

The hyperfine structure (hfs) of electron levels of $^{238}_{92}$U ions with the nucleus excited in the low-lying rotational $2^+$ state with an energy $E_{2^+} = 44.91$ keV is investigated. In hydrogenlike uranium, the hfs splitting for…

Quantum Physics · Physics 2009-10-31 L. N. Labzowsky , A. V. Nefiodov , G. Plunien , G. Soff , D. Liesen

We present results of the first experiment to probe for the electric dipole moment (EDM) of the electron using an $\Omega$-doublet state in a polar molecule. If the molecule is both massive and has a large molecular-fixed frame dipole…

Atomic Physics · Physics 2015-06-15 S. Eckel , P. Hamilton , E. Kirilov , H. W. Smith , D. DeMille

Electric quadrupole (E2) and magnetic dipole (M1) transition amplitudes among the low-lying states of quadruply ionized vanadium V$^{4+}$, important in various field of experimental and astrophysics are presented very accurately. Most of…

Atomic Physics · Physics 2009-11-13 Gopal Dixit , B. K. Sahoo , P. C. Deshmukh , R. K. Chaudhuri , Sonjoy Majumder

Despite its apparently simple nature with four valence electrons, the strontium dimer constitutes a challenge for modern electronic structure theory. Here we focus on excited electronic states of Sr$_2$, which we investigate theoretically…

We consider a disordered two-dimensional electronic system in the limit of high magnetic field at the metal-insulator transition. Density of states close to the Fermi level acquires a divergent correction to the lowest order in…

Condensed Matter · Physics 2009-10-28 Igor F. Herbut , Zlatko Tesanovic

Aluminum monofluoride (AlF) is a suitable molecule for laser cooling and trapping. Such experiments require an extensive spectroscopic characterization of the electronic structure. Two of the theoretically predicted higher lying triplet…

Chemical Physics · Physics 2024-03-05 N. Walter , M. Doppelbauer , S. Schaller , X. Liu , R. Thomas , S. Wright , B. G. Sartakov , G. Meijer