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Related papers: Enhanced Molecular Orientation Induced by Molecula…

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We show that field-free molecular orientation induced by a half-cycle pulse may be considerably enhanced by an additional laser pulse inducing molecular anti-alignment. Two qualitatively different enhancement mechanisms are identified…

Quantum Physics · Physics 2009-11-11 E. Gershnabel , I. Sh. Averbukh , R. J. Gordon

The field-free alignment and orientation of the linear molecule by the two-color trapezoidal laser pulses were theoretically investigated. The trapezoidal shape of a laser pulse allows to enhance the maximum alignment degree for the same…

Quantum Physics · Physics 2024-01-11 Eugene A. Koval

We review on the theoretical status of intense laser orientation and alignment. The evolution of the rotational wave packet and its dynamics leading to orientation and alignment is the topic of the present discussion. The major part of the…

Atomic Physics · Physics 2021-04-14 Vijit V. Nautiyal , Sumana Devi , Ashish Tyagi , Bhawna Vidhani , Anjali Maan , Vinod Prasad

We study interaction of generic asymmetric molecules with a pair of strong time-delayed short laser pulses with crossed linear polarizations. We show that such an excitation not only provides unidirectional rotation of the most polarizable…

Chemical Physics · Physics 2018-02-28 E. Gershnabel , I. Sh. Averbukh

We show that circularly polarized femtosecond laser pulses produce field-free alignment in linear and planar molecules. We study the rotational wavepacket evolution of O$_2$ and benzene created by circularly polarized light. For benzene, we…

Chemical Physics · Physics 2014-06-06 C T L Smeenk , P B Corkum

Alignment and orientation of molecules by intense, ultrashort laser fields are crucial for a variety of applications in physics and chemistry. These include control of high harmonics generation, molecular orbitals tomography, control of…

We show that a combination of a half-cycle pulse and a short nonresonant laser pulse produces a strongly enhanced postpulse orientation. Robust transients that display both efficient and long-lived orientation are obtained. The mechanism is…

Quantum Physics · Physics 2007-05-23 D. Daems , S. Guérin , D. Sugny , H. R. Jauslin

Half-cycle laser pulse is applied on an absorbed molecule to investigate its alignment and orientation behavior. Crossover from field-free to hindered rotation motion is observed by varying the angel of hindrance of potential well. At small…

Atomic Physics · Physics 2007-05-23 Y. Y. Liao , Y. N. Chen , D. S. Chuu

We study the excitation of asymmetric-top (including chiral) molecules by two-color femtosecond laser pulses. In the cases of non-chiral asymmetric-top molecules excited by an orthogonally polarized two-color pulse, we demonstrate,…

Optics · Physics 2021-09-16 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

We theoretically consider the phenomenon of field-free long-lasting orientation of symmetric-top molecules ionized by two-color laser pulses. The anisotropic ionization produces a significant long-lasting orientation of the surviving…

Chemical Physics · Physics 2023-03-08 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

We present a comprehensive study of enantioselective orientation of chiral molecules excited by a pair of delayed cross-polarized femtosecond laser pulses. We show that by optimizing the pulses' parameters, a significant (~ 10%) degree of…

Optics · Physics 2022-07-20 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

Enantioselective orientation of chiral molecules excited by a shaped picosecond laser pulse and a delayed femtosecond pulse is considered. Using quantum mechanical simulations, we demonstrate a strong field-free enantioselective orientation…

Optics · Physics 2022-03-31 Long Xu

Two mechanisms of two-color (\omega + 2\omega) laser-induced field-free molecular orientation, based on the hyperpolarizability and ionization depletion, are explored and compared. The CO molecule is used as a computational example. While…

Atomic Physics · Physics 2012-09-14 Michael Spanner , Serguei Patchkovskii , Eugene Frumker , Paul Corkum

Impulsive orientation of symmetric-top molecules excited by two-color femtosecond pulses is considered. In addition to the well-known transient orientation appearing immediately after the pulse and then reemerging periodically due to…

Optics · Physics 2021-07-22 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

A strong inhomogeneous static electric field is used to spatially disperse a rotationally cold supersonic beam of 2,6-difluoroiodobenzene molecules according to their rotational quantum state. The molecules in the lowest lying rotational…

We have experimentally and theoretically investigated the mixed-field orientation of rotational-state-selected OCS molecules and we achieve strong degrees of alignment and orientation. The applied moderately intense nanosecond laser pulses…

An investigation of field-free molecular alignment produced by elliptically polarized laser pulses is reported. Experiments are conducted in CO$_2$ at room temperature. A non invasive all-optical technique, based on the cross defocusing of…

Quantum Physics · Physics 2008-12-18 E. Hertz , D. Daems , S. Guérin , H. R. Jauslin , B. Lavorel , O. Faucher

Genetic algorithms, as implemented in optimal control strategies, are currently successfully exploited in a wide range of problems in molecular physics. In this context, laser control of molecular alignment and orientation remains a very…

Chemical Physics · Physics 2007-05-23 O. Atabek , C. M. Dion

Ultrashort laser pulses are widely used for transient field-free molecular orientation -- a phenomenon important in chemical reaction dynamics, ultrafast molecular imaging, high harmonics generation, and attosecond science. However,…

Chemical Physics · Physics 2022-12-21 Ilia Tutunnikov , Long Xu , Yehiam Prior , Ilya Sh. Averbukh

The mixed-field orientation of an asymmetric-rotor molecule with its permanent dipole moment non-parallel to the principal axes of polarizability is investigated experimentally and theoretically. We find that for the typical case of a…

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