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Easy physics-inspired approximations of the total and binding energies for the ${\rm H}$ atom and for the molecular ions $${\rm H}_2^{(+)} ({\rm ppe}), {\rm H}_3^{(2+)} ({\rm pppe}), ({\rm HeH})^{++} (\al {\rm p e}), {\rm He}_2^{(3+)} (\al…

Atomic Physics · Physics 2007-05-23 A. V. Turbiner , A. B. Kaidalov , J. C. Lopez Vieyra

For interacting electrons in solids, Heisenberg's equation is used to calculate the distribution in energy of transitions induced by adding an electron to an atomic-like spin orbital. This is the projected density of transitions which…

Strongly Correlated Electrons · Physics 2017-02-15 Roger Haydock

Matching for a wavefunction the WKB expansion at large distances and Taylor expansion at small distances leads to a compact, few-parametric uniform approximation found in {\it J. Phys. B44, 101002 (2011)}. The ten low-lying eigenstates of…

Quantum Physics · Physics 2019-08-13 Horacio Olivares-Pilón , Alexander V. Turbiner

In this work we calculate the correction to the ground state energy of the hydrogen atom due to contributions arising from the presence of a minimal length. The minimal length scenario is introduced by means of modifying the Dirac equation…

High Energy Physics - Theory · Physics 2015-06-16 T. L. Antonacci Oakes , R. O. Francisco , J. C. Fabris , J. A. Nogueira

In the present work ferromagnetic ordering in the Hubbard model generalized by taking into account the inter-atomic exchange interaction and correlated hopping in partially filled narrow band is considered. In the case of weak…

Strongly Correlated Electrons · Physics 2007-05-23 L. Didukh , O. Kramar , Yu. Skorenkyy

It is generally believed that the old quantum theory, as presented by Niels Bohr in 1913, fails when applied to few electron systems, such as the H2 molecule. Here we find new solutions within the Bohr theory that describe the potential…

Chemical Physics · Physics 2009-11-11 Anatoly A. Svidzinsky , Marlan O. Scully , Dudley R. Herschbach

We develop a model of molecular binding based on the Bohr-Sommerfeld description of atoms together with a constraint taken from conventional quantum mechanics. The model can describe the binding energy curves of H2, H3 and other molecules…

Chemical Physics · Physics 2009-11-11 Anatoly A. Svidzinsky , Siu A. Chin , Marlan O. Scully

We present precision measurements with MHz uncertainty of the energy gap between asymptotic and well bound levels in the electronic ground state X $^1\Sigma_{\mathrm{g}}^+$ of the $^{39}$K$_2$ molecule. The molecules are prepared in a…

Minimizing the energy of an $N$-electron system as a functional of a two-electron reduced density matrix (2-RDM), constrained by necessary $N$-representability conditions (conditions for the 2-RDM to represent an ensemble $N$-electron…

Chemical Physics · Physics 2016-06-21 Nicholas C. Rubin , David A. Mazziotti

We discuss an approach to accurate numerical computations of slowly convergent properties in two-electron atoms/ions which include the negatively charged Ps$^{-}$ ($e^{-} e^{+} e^{-}$) and H$^{-}$ ions, He atom and positively charged,…

Atomic Physics · Physics 2016-09-21 Alexei M. Frolov , David M. Wardlaw

As a continuation of our previous work ({\it Phys. Rev. A68, 012504 (2003)}) an accurate study of the lowest $1\si_g$ and the low-lying excited $1\si_u$, $2\si_g$, $1\pi_{u,g}$, $1\de_{g,u}$ electronic states of the molecular ion $H_2^+$ is…

Astrophysics · Physics 2008-11-26 A. V. Turbiner , J. C. Lopez Vieyra

The variational Monte Carlo method is used to evaluate the ground-state energy of the confined hydrogen molecule, H_2. Accordingly, we considered the case of hydrogen molecule confined by a hard prolate spheroidal cavity when the nuclear…

Atomic and Molecular Clusters · Physics 2015-09-10 S. B. Doma , F. N. El-Gammal , A. A. Amer

The static dipole polarizabibility for the $1s\sigma$ electron state of the $\mathrm{H}_{2}^{+}$ hydrogen molecular ion is calculated within Born-Oppenheimer approximation. The variational expansion with randomly chosen exponents has been…

Atomic Physics · Physics 2010-07-27 Ts. Tsogbayar

We consider a model of three electrons and one hole confined in a two-dimensional (2D) plane, interacting with one another through Coulomb forces. Using a Ritz variational method we find an upper bound of \approx -0.0112me^4/8\pi^2 \epsilon…

Strongly Correlated Electrons · Physics 2007-05-23 Nie Luo

Highly accurate nonrelativistic ground-state wave function and energy of the lithium atom is obtained in the Hylleraas basis set. The leading relativistic corrections,as represented by Breit-Pauli Hamiltonian, are obtained in fair agreement…

Atomic Physics · Physics 2009-11-11 Mariusz Puchalski , Krzysztof Pachucki

Following the ideas behind the Feynman approach, a variational wave function is proposed for the Fr\"ohlich model. It is shown that it provides, for any value of the electron-phonon coupling constant, an estimate of the polaron ground state…

Strongly Correlated Electrons · Physics 2009-11-10 G. De Filippis , V. Cataudella , V. Marigliano Ramaglia , C. A. Perroni , D. Bercioux

We study the energy levels of H$_2$ molecules in a superstrong magnetic field ($B\go 10^{12}$ G), typically found on the surfaces of neutron stars. The interatomic interaction potentials are calculated by a Hartree-Fock method with…

Astrophysics · Physics 2009-10-28 Dong Lai , Edwin E. Salpeter

The Pauli-Hamiltonian of a molecule with fixed nuclei in a strong constant magnetic field is asymptotic, in norm-resolvent sense, to an effective Hamiltonian which has the form of a multi-particle Schr\"odinger operator with interactions…

Mathematical Physics · Physics 2012-08-16 Mathieu Beau , Rafael Benguria , Raymond Brummelhuis , Pierre Duclos

An approximation for the exchange-correlation energy of reduced-density-matrix-functional theory was recently derived from a study of the homogeneous electron gas (N.N. Lathiotakis, N. Helbig, E.K.U. Gross, Phys. Rev. B 75, 195120 (2007)).…

Strongly Correlated Electrons · Physics 2009-11-13 N. N. Lathiotakis , N. Helbig , A. Zacarias , E. K. U. Gross

We present an effective theory describing the low-energy properties of an interacting 2D electron gas at large non-integer filling factors $\nu\gg 1$. Assuming that the interaction is sufficiently weak, $r_s < 1$, we integrate out all the…

Condensed Matter · Physics 2009-10-28 I. L. Aleiner , L. I. Glazman
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