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We introduce the Anharmonic Oscillator Symmetry Model to describe vibrational excitations in molecular systems exhibiting high degree of symmetry. A systematic procedure is proposed to establish the relation between the algebraic and…

chem-ph · Physics 2009-10-28 A. Frank , R. Lemus , R. Bijker , F. Perez-Bernal , J. M. Arias

We propose an accurate and efficient method to compute vibrational spectra of molecules, based on exact diagonalization of an algebraically calculated matrix based on powers of Morse coordinate. The present work focuses on the 1D potential…

Chemical Physics · Physics 2009-11-13 Andrea Bordoni , Nicola Manini

We propose a new approach to calculate perturbatively the effects of a particular deformed Heisenberg algebra on energy spectrum. We use this method to calculate the harmonic oscillator spectrum and find that corrections are in agreement…

Quantum Physics · Physics 2008-11-26 F. Brau

An algebraic model based on Lie-algebraic techniques is applied to the analysis of thermodynamic vibrational properties of diatomic molecules. The local anharmonic effects are described by a Morse-like potential and corresponding anharmonic…

Statistical Mechanics · Physics 2007-05-23 Maia Angelova , A. Frank

We review the essentials of the formalism of quantum mechanics based on a deformed Heisenbeg algebra, leading to the existence of a minimal length scale. We compute in this context, the energy spectra of the pseudoharmonic oscillator and…

Quantum Physics · Physics 2017-11-15 Djamil Bouaziz

An algebraic model based on Lie-algebraic and discrete symmetry techniques is applied to the analysis of thermodynamic vibrational properties of molecules. The local anharmonic effects are described by a Morse-like potential and the…

Statistical Mechanics · Physics 2017-08-23 Maia Angelova , A. Frank

We provide the time evolutions of the linear and nonlinear coherent states for several systems characterized by different energy spectra, and we identify the regions in the parameter space where these systems behave closer to the classical…

Quantum Physics · Physics 2018-05-29 A. Belfakir , Y. Hassouni

We analyze the gravitational wave signals with a model-independent time-frequency analysis, which is improved from the Hilbert-Huang transform (HHT) and optimized for characterizing the frequency variability on the time-frequency map.…

High Energy Astrophysical Phenomena · Physics 2022-08-31 Chin-Ping Hu , Lupin Chun-Che Lin , Kuo-Chuan Pan , Kwan-Lok Li , Chien-Chang Yen , Albert K. H. Kong , C. Y. Hui

We present a simple and efficient method to incorporate anharmonic effects in the vibrational \textcolor{black}{analyses} of molecules within density functional theory (DFT) calculations. This approach is closely related to the traditional…

Interacting dipole ($p$) bosons along with scalar ($s$) bosons, based on the ideas drawn from the interacting boson model of atomic nuclei, led to the development of the vibron model based on $U(4)$ spectrum generating algebra for diatomic…

Chemical Physics · Physics 2021-07-15 V. K. B. Kota

For arbitrary values n and l quantum numbers, we present the solutions of the 3-dimensional Schrodinger wave equation with the pseudoharmonic potential via SU(1,1) Spectrum Generating Algebra (SGA) approach. The explicit bound state…

Chemical Physics · Physics 2011-05-12 K. J. Oyewumi , K. D. Sen

We apply the Anharmonic Oscillator Symmetry Model to the description of vibrational excitations in ${\cal D}_{3h}$ and ${\cal T}_d$ molecules. A systematic procedure can be used to establish the relation between the algebraic and…

chem-ph · Physics 2008-02-03 A. Frank , R. Lemus , R. Bijker , F. Perez-Bernal , J. M. Arias

The radial time-independent Schr\"odinger equation is solved for the diatomic molecules: H2, LiH, HCl, CO, VH, CrH, CuLi, TiC, NiC, and ScN using the recently developed Nikiforov-Uvarov Functional Analysis (NUFA) method. A modified Morse…

Chemical Physics · Physics 2024-10-01 Raghav Sharma , Pragati Ashdhir , Amit Tanwar

We describe a new approach based on semiclassical molecular dynamics that allows to simulate infrared absorption or emission spectra of molecular systems with inclusion of anharmonic intensities. This is achieved from semiclassical power…

Chemical Physics · Physics 2018-11-12 Marco Micciarelli , Riccardo Conte , Jaime Suarez , Michele Ceotto

The dynamical algebra associated to a family of isospectral oscillator Hamiltonians is studied through the analysis of its representation in the basis of energy eigenstates. It is shown that this representation becomes similar to that of…

High Energy Physics - Theory · Physics 2009-09-25 David J. Fernández C. , Luis M. Nieto , Oscar Rosas-Ortiz

A new spectrum generating algebra for a unified description of rotations and vibrations in polyatomic molecules is introduced. An application to nonlinear X$_3$ molecules shows that this model (i) incorporates exactly the relevant point…

chem-ph · Physics 2009-10-28 R. Bijker , A. E. L. Dieperink , A. Leviatan

We construct a generalised expression for the normal ordering of (a+a^{\dagger})^{m} for integral values of m and use the result to study the quantum anharmonic oscillator problem in the Heisenberg approach. In particular, we derive…

Mathematical Physics · Physics 2007-05-23 Anirban Pathak

Lie-algebraic and quantum-algebraic techniques are used in the analysis of thermodynamic properties of molecules and solids. The local anharmonic effects are described by a Morse-like potential associated with the $su(2)$ algebra. A…

Statistical Mechanics · Physics 2007-05-23 Maia Angelova

The computation of vibrational spectra of diatomic molecules through the exact diagonalization of algebraically determined matrixes based on powers of Morse coordinates is made substantially more efficient by choosing a properly adapted…

Chemical Physics · Physics 2016-09-28 Andrea Bordoni , Nicola Manini

This work presents the bound-state spectra of Morse oscillator, which remains one of the oldest important model potentials for molecules. Accurate ro-vibrational energies are obtained by means of a generalized pseudospectral method that…

Quantum Physics · Physics 2013-07-19 Amlan K. Roy
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