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We report theoretical investigations of the tomographic procedure suggested by Itatani {\it et al.} [Nature, {\bf 432} 867 (2004)] for reconstructing highest occupied molecular orbitals (HOMO) using high-order harmonic generation (HHG).…

Atomic Physics · Physics 2009-10-30 Van-Hoang Le , Anh-Thu Le , Rui-Hua Xie , C. D. Lin

The Heisenberg algebra is deformed with the set of parameters ${q, l,\lambda}$ to generate a new family of generalized coherent states respecting the Klauder criteria. In this framework, the matrix elements of relevant operators are exactly…

Mathematical Physics · Physics 2012-11-15 Joseph Désiré Bukweli , Mahouton Norbert Hounkonnou

The General Spectral Modeling (GSM) code employs the quasi-static approximation, a standard, low-density methodology that assumes the ionization balance is separable from a determination of the excited-state populations that give rise to…

Atomic Physics · Physics 2008-11-26 Justin Oelgoetz , Christopher J. Fontes , Hong Lin Zhang , Anil K. Pradhan

In this article, we demonstrate the restricted Hartree-Fock electronic structure computation of the molecule $H_3^+$ through computational algebra. We approximate the Hartree-Fock total energy by a polynomial composed of LCAO coefficients…

Computational Physics · Physics 2024-05-15 Ichio Kikuchi , Akihito Kikuchi

We propose a new method for a numerical computation of the angular bispectrum of the CMB anisotropies arising from active models such as cosmic topological defects, using a modified Boltzmann code based on CMBFAST. The method does not use…

Astrophysics · Physics 2009-11-06 Alejandro Gangui , Levon Pogosian , Serge Winitzki

In this article, we propose a generalized non-equilibrium chemical kinetics model from \textit{ab initio} simulation data obtained using accurate potential energy surfaces developed recently for the purpose of studying high-temperature air…

Fluid Dynamics · Physics 2020-07-15 Narendra Singh , Thomas Schwartzentruber

We report a three-dimensional numerical implementation of multiconfiguration time-dependent Hartree-Fock (MCTDHF) based on a multi-resolution Cartesian grid, with no need to assume any symmetry of molecular structure. We successfully…

Computational Physics · Physics 2016-03-23 Ryohto Sawada , Takeshi Sato , Kenichi L. Ishikawa

We study gravitational-wave production from bubble collisions in a cosmic first-order phase transition, focusing on the possibility of model separation by the bubble nucleation rate dependence of the resulting gravitational-wave spectrum.…

High Energy Physics - Phenomenology · Physics 2018-03-20 Ryusuke Jinno , Sangjun Lee , Hyeonseok Seong , Masahiro Takimoto

Determining the vibrational structure of a molecule is central to fundamental applications in several areas, from atmospheric science to catalysis, fuel combustion modeling, biochemical imaging, and astrochemistry. However, when significant…

Quantum Physics · Physics 2021-12-22 Nicolas P. D. Sawaya , Francesco Paesani , Daniel P. Tabor

Recent neural network-based wave functions have achieved state-of-the-art accuracies in modeling ab-initio ground-state potential energy surface. However, these networks can only solve different spatial arrangements of the same set of…

Machine Learning · Computer Science 2023-06-01 Nicholas Gao , Stephan Günnemann

Reporting extensions of a recently developed approach to density functional theory with correct long-range be-havior (Phys. Rev. Lett. 94, 043002 (2005)). The central quantities are a splitting functional gamma[n] and a complementary…

Materials Science · Physics 2017-09-13 Ester Livshits , Roi Baer

The atomic motion in molecular crystals, such as high-pressure hydrogen or hybrid organic-inorganic perovskites, is very complex due to quantum anharmonic effects. In addition, these materials accommodate rotational degrees of freedom. All…

Materials Science · Physics 2024-10-04 Antonio Siciliano , Lorenzo Monacelli , Francesco Mauri

A family of Variational Quantum Eigensolver (VQE) methods is designed to maximize the resource of existing noisy intermediate-scale quantum (NISQ) devices. However, VQE approaches encounter various difficulties in simulating molecules of…

Chemical Physics · Physics 2022-08-16 M. D. Sapova , A. K. Fedorov

The particle-based ellipsoidal statistical Bhatnagar-Gross-Krook (ESBGK) model is extended to diatomic molecules and compared with the Direct Simulation Monte Carlo (DSMC) method. For this an efficient method is developed that optionally…

Computational Physics · Physics 2018-11-09 Marcel Pfeiffer

We derive a Hierarchical Equations of Motion (HEOM) description of nonadiabatic Herzberg-Teller type coupling effects and of non-Condon effects in a system of electronic transitions interacting with intra- and inter-molecular vibrational…

Chemical Physics · Physics 2018-12-26 Joachim Seibt , Tomáš Mančal

The Heisenberg algebra is first deformed with the set of parameters ${q, l, \lambda}$ to generate a new family of generalized coherent states. In this framework, the matrix elements of relevant operators are exactly computed. A proof on…

Mathematical Physics · Physics 2013-01-03 J. D. Bukweli-Kyemba , M. N. Hounkonnou

We present the implementation of a variational finite element solver in the HelFEM program for benchmark calculations on diatomic systems. A basis set of the form $\chi_{nlm}(\mu,\nu,\phi)=B_{n}(\mu)Y_{l}^{m}(\nu,\phi)$ is used, where…

Chemical Physics · Physics 2019-08-19 Susi Lehtola

Exact solutions for vibrational levels of diatomic molecules via the Morse potential are obtained by means of the asymptotic iteration method. It is shown that, the numerical results for the energy eigenvalues of $^{7}Li_{2}$ are all in…

Quantum Physics · Physics 2009-11-13 T. Barakat , K. Abodayeh

We show that graphene, in its simplest form and settings, is a practical table-top realization of the analog of exotic quantum gravity scenarios, which are speculated to lead to certain generalized Heisenberg algebras. In particular, we…

General Relativity and Quantum Cosmology · Physics 2022-12-22 Alfredo Iorio , Boris Ivetić , Salvatore Mignemi , Pablo Pais

The electronic structures and optical properties of cubic HfO2 are calculated by means of generalized gradient approximation (GGA) +U approach. Without on-site Coulomb interactions, the band gap of cubic HfO2 is 2.92eV, much lower than the…

Materials Science · Physics 2013-11-26 Jinping Li , Songhe Meng , Lingling Li , Hantao Lu , Takami Tohyama
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