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Understanding collisions between ultracold molecules is crucial for making stable molecular quantum gases and harnessing their rich internal degrees of freedom for quantum engineering. Transient complexes can strongly influence collisional…

Ultracold polar molecules offer strong electric dipole moments and rich internal structure, which makes them ideal building blocks to explore exotic quantum matter, implement novel quantum information schemes, or test fundamental symmetries…

The study of ultracold molecules tightly trapped in an optical lattice can expand the frontier of precision measurement and spectroscopy, and provide a deeper insight into molecular and fundamental physics. Here we create, probe, and image…

Atomic Physics · Physics 2015-12-22 B. H. McGuyer , M. McDonald , G. Z. Iwata , M. G. Tarallo , A. T. Grier , F. Apfelbeck , T. Zelevinsky

We derive the equilibrium conditions for a thermal atom-molecule mixture near a Feshbach resonance. Under the assumption of low collisional loss, thermodynamical properties are calculated and compared to the measurements of a recent…

Soft Condensed Matter · Physics 2007-05-23 Cheng Chin , Rudolf Grimm

Ultracold molecules represent a fascinating research frontier in physics and chemistry, but it has proven challenging to prepare dense samples at low velocities. Here we present a solution to this goal by a non-conventional approach dubbed…

Atomic Physics · Physics 2018-12-04 Xing Wu , Thomas Gantner , Manuel Koller , Martin Zeppenfeld , Sotir Chervenkov , Gerhard Rempe

Besides being a source of energy, light can also cool gases of atoms down to the lowest temperatures ever measured, where atomic motion almost stops. The research field of cold atoms has emerged as a multidisciplinary one, highly relevant,…

Atomic Physics · Physics 2015-06-22 Leonardo Fallani , Anders Kastberg

In weakly bound diatomic molecules, energy levels are closely spaced and thus more susceptible to mixing by magnetic fields than in the constituent atoms. We use this effect to control the strengths of forbidden optical transitions in…

Atomic Physics · Physics 2015-12-22 B. H. McGuyer , M. McDonald , G. Z. Iwata , W. Skomorowski , R. Moszynski , T. Zelevinsky

Ultracold plasmas are formed by photo-exciting clouds of cold atoms and molecules near the ionization threshold. They explore a new region of plasma physics and display effects of strong coupling, which is characterized by a ratio of…

Plasma Physics · Physics 2012-01-05 J. Castro , P. McQuillen , H. Gao , T. C. Killian

We show that the electric dipole-dipole interaction between a pair of polar molecules undergoes an all-out transformation when superimposed by a far-off resonant optical field. The combined interaction potential becomes tunable by variation…

Atomic Physics · Physics 2015-05-30 Mikhail Lemeshko , Bretislav Friedrich

We investigate the presence of Feshbach resonances in ultracold alkali-dialkali reactive collisions. Quantum scattering calculations are performed on a new Na_3 quartet potential energy surface. An analysis of scattering features is…

Quantum Physics · Physics 2009-11-13 A. Simoni , J-M. Launay , P. Soldan

We calculate the interaction potential between N atoms and NH molecules and use it to investigate cold and ultracold collisions important for sympathetic cooling. The ratio of elastic to inelastic cross sections is large over a wide range…

Chemical Physics · Physics 2011-02-23 Piotr S. Żuchowski , Jeremy M. Hutson

We demonstrate that the critical temperature for valence tautomeric interconversion in Cobalt dioxolene complexes can be significantly changed when a static electric field is applied to the molecule. This is achieved by effectively…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 Andrea Droghetti , Stefano Sanvito

The presence of electric or microwave fields can modify the long-range forces between ultracold dipolar molecules in such a way as to engineer weakly-bound states of molecule pairs. These so-called field-linked states [Avdeenkov et al.,…

Atomic Physics · Physics 2024-06-21 Goulven Quéméner , John L. Bohn , James F. E. Croft

In this article, we present emerging fields of quantum chemistry at finite temperature. We discuss its recent developments on both experimental and theoretical fronts. First, we describe several experimental investigations related to the…

Soft Condensed Matter · Physics 2007-05-23 Liqiang Wei

Collisions between ultracold calcium monohydroxide (CaOH) molecules are realized and studied. Inelastic collision rate constants are measured for CaOH prepared in ground and excited vibrational states, and the electric field dependence of…

Understanding ultracold collisions involving molecules is of fundamental importance for current experiments, where inelastic collisions typically limit the lifetime of molecular ensembles in optical traps. Here we present a broad study of…

'Oriented external electric fields (OEEFs)' have been shown to have great potential in being able to provide unprecedented control of chemical reactions, catalysis and selectivity with applications ranging from H2 storage to molecular…

Chemical Physics · Physics 2020-07-01 Shahin Sowlati-Hashjin , Mikko Karttunen , Cherif F. Matta

A theoretical model is proposed for the formation of ultracold ground-state triatomic molecules in weakly bound energy levels. The process is driven by the electric component of a microwave field, which induces the association of an…

Atomic Physics · Physics 2026-01-16 Baraa Shammout , Leon Karpa , Silke Ospelkaus , Eberhard Tiemann , Olivier Dulieu

Ultracold collisions of LiO molecules in the $^{2}\Pi_{3/2}$ ground state are considered, under the influence of either an external magnetic or electric field. Inelastic collisions are shown to be suppressed in the presence of modest…

Atomic Physics · Physics 2020-09-16 Lucie D. Augustovičová , John L. Bohn

We prove that for a combined system of classical and quantum particles, it is possible to write a dynamics for the classical particles that incorporates in a natural way the Boltzmann equilibrium population for the quantum subsystem. In…

Other Condensed Matter · Physics 2010-09-01 J. L. Alonso , A. Castro , P. Echenique , V. Polo , A. Rubio , D. Zueco
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