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We use accurate quantum mechanical calculations to analyze the effects of parallel electric and magnetic fields on collision dynamics of OH(2Pi) molecules. It is demonstrated that spin relaxation in 3He-OH collisions at temperatures below…

Atomic Physics · Physics 2012-02-06 Timur V. Tscherbul , Gerrit C. Groenenboom , Roman V. Krems , Alex Dalgarno

We consider collisions of electric and magnetic polar molecules, taking the OH radical as an example, subject to combined electric and magnetic static fields. We show that the relative orientation of the fields has an important effect on…

Atomic Physics · Physics 2013-07-16 Goulven Quéméner , John L. Bohn

We investigate the collisional stability of magnetically trapped ultracold molecules, taking into account the influence of magnetic fields. We compute elastic and spin-state-changing inelastic rate constants for collisions of the prototype…

Quantum Physics · Physics 2009-11-07 Alessandro Volpi , John L. Bohn

We report the magnetic confinement of neutral, ground state hydroxyl radicals (OH) at a density of $\sim3\times10^{3}$ cm$^{-3}$ and temperature of $\sim$30 mK. An adjustable electric field of sufficient magnitude to polarize the OH is…

Cold collisions of $^{14}$N$^{16}$O molecules in the $^{2}\Pi_{1/2}$ ground state, subject to electric and magnetic fields, are investigated. It is found that elastic collision rates significantly exceed state-changing inelastic rates only…

Atomic Physics · Physics 2017-10-25 Lucie D. Augustovičová , John L. Bohn

Ultracold collisions of polar OH molecules are considered in the presence of an electrostatic field. The field exerts a strong influence on both elastic and state-changing inelastic collision rate constants, leading to clear experimental…

Atomic Physics · Physics 2009-11-07 Alexandr V. Avdeenkov , John L. Bohn

We present quantum-theoretical studies of collisions between an open-shell S-state atom and a ^2Pi-state molecule in the presence of a magnetic field. We analyze the collisional Hamiltonian and discuss possible mechanisms for inelastic…

Collision cross sections and rate constants between two ground- state oxygen molecules are investigated theoretically at translational energies below $\sim 1$K and in zero magnetic field. We present calculations for elastic and spin-…

Atomic Physics · Physics 2009-11-07 Alexandr V. Avdeenkov , John L. Bohn

We describe a method for cooling neutral molecules that have magnetic and electric dipole moments using collisions with cold ions. An external magnetic field is used to split the ground rovibrational energy levels of the molecule. The…

Atomic Physics · Physics 2014-08-22 F. Robicheaux

Collisions of polar $^{1}\Sigma$ state molecules at ultralow energies are considered, within a model that accounts for long-range dipole-dipole interactions, plus rotation of the molecules. We predict a substantial suppression of…

Atomic Physics · Physics 2016-09-08 Alexander V. Avdeenkov , Masatoshi Kajita , John L. Bohn

Ultracold collisions of LiO molecules in the $^{2}\Pi_{3/2}$ ground state are considered, under the influence of either an external magnetic or electric field. Inelastic collisions are shown to be suppressed in the presence of modest…

Atomic Physics · Physics 2020-09-16 Lucie D. Augustovičová , John L. Bohn

The collisional stability of ultracold polar molecules in electrostatic traps is considered. Rate constants for collisions that drive molecules from weak-field-seeking to strong-field-seeking states are estimated using a simple model. The…

Atomic Physics · Physics 2009-11-06 John L. Bohn

We theoretically investigate trapping conditions for ultracold polar molecules in optical lattices, when external magnetic and electric fields are simultaneously applied. Our results are based on an accurate electronic-structure calculation…

Quantum Physics · Physics 2017-08-29 Ming Li , Alexander Petrov , Constantinos Makrides , Eite Tiesinga , Svetlana Kotochigova

We present an accurate quantum mechanical study of molecule-molecule collisions in the presence of a magnetic field. The work focusses on the analysis of elastic scattering and spin relaxation in collisions of O2(3Sigma_g) molecules at cold…

Atomic Physics · Physics 2012-02-06 T. V. Tscherbul , Yu. V. Suleimanov , V. Aquilanti , R. V. Krems

We present the first experimental observation of cold collisions between two different species of neutral polar molecules, each prepared in a single internal quantum state. Combining for the first time the techniques of Stark deceleration,…

We calculate the interaction potential between N atoms and NH molecules and use it to investigate cold and ultracold collisions important for sympathetic cooling. The ratio of elastic to inelastic cross sections is large over a wide range…

Chemical Physics · Physics 2011-02-23 Piotr S. Żuchowski , Jeremy M. Hutson

Collisions between cold molecules are essential for studying fundamental aspects of quantum chemistry, and may enable formation of quantum degenerate molecular matter by evaporative cooling. However, collisions between trapped, naturally…

Cold ($T\sim 10^{4} \ \mathrm{K}$) gas is very commonly found in both galactic and cluster halos. There is no clear consensus on its origin. Such gas could be uplifted from the central galaxy by galactic or AGN winds. Alternatively, it…

Astrophysics of Galaxies · Physics 2018-07-10 Suoqing Ji , S. Peng Oh , Michael McCourt

We demonstrate the long-term ($<$ 1 minute) trapping of Stark-decelerated OH radicals in their $X~^{2}\Pi _{3/2}~(\nu = 0,~J = 3/2,~M_{J} = 3/2,~f)$ state in a permanent magnetic trap. The trap environment was cryogenically cooled to a…

Chemical Physics · Physics 2019-08-05 Dominik Haas , Claudio von Planta , Thomas Kierspel , Dongdong Zhang , Stefan Willitsch

We predict that pairs of polar molecules can be weakly bound together in an ultracold environment, provided that a dc electric field is present. The field that links the molecules together also strongly influences the basic properties of…

Atomic Physics · Physics 2009-11-07 A. V. Avdeenkov , J. L. Bohn
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