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The structure and thickness of the electrical double layer (EDL) at carbon electrodes strongly influence electrochemical performance, yet remain poorly understood in super-concentrated aqueous electrolytes. Here we combine classical and…

A major challenge in modelling interfacial processes in electrochemical (EC) devices is performing simulations at constant potential. This requires an open-boundary description of the electrons, so that they can enter and leave the…

Chemical Physics · Physics 2023-11-07 Margherita Buraschi , Andrew P. Horsfield , Clotilde S. Cucinotta

A large electric field is typically present in anodic or passive oxide films. Stresses induced by such a large electric field are critical in understanding the breakdown mechanism of thin oxide films and improving their corrosion…

Materials Science · Physics 2024-04-26 Jin Zhang , Peter W. Voorhees

We study the patterns at which the current flow stabilizes in a 1D superconducting wire, for various experimentally reasonable boundary conditions, for small fixed current densities and temperatures close to $T_c$. We pay special attention…

Superconductivity · Physics 2015-08-26 Jorge Berger

Charge ordering (CO) phenomena have been widely debated in strongly-correlated electron systems mainly regarding their role in high-temperature superconductivity. Here, we elucidate the structural and charge distribution in NdNiO$_{2}$ thin…

In this paper we analyze again a transition from the classical to quantum description of bound charged particles, which involves a substantial modification of the structure of their electromagnetic (EM) fields related to the well-known fact…

Atomic Physics · Physics 2011-03-22 T. Yarman , A. L. Kholmetskii , O. V. Missevitch

The stability against quench is one of the main issue to be pursued in a superconducting material which should be able to perform at very high levels of current densities. Here we focus on the connection between the critical current $I_c$…

Electric double layer (EDL) formation underlies the functioning of supercapacitors and several other electrochemical technologies. Here, we study how the EDL formation near two flat blocking electrodes separated by $2L$ is affected by…

Chemical Physics · Physics 2025-09-23 David Fertig , Mathijs Janssen

Using Landau-Ginzburg-Devonshire theory, we considered the impact of the flexoelectro-chemical coupling on the size effects inpolar properties and phase transitions of thin ferroelectric films with a layer of elastic defects. We…

Polycrystalline solids can exhibit material properties that differ significantly from those of equivalent single-crystal samples, in part, because of a spontaneous redistribution of mobile point defects into so-called space-charge regions…

The electro-osmotic flow (EOF) in a neutral system consisting of an aqueous NaCl solution confined in a nanochannel with two parallel Molybdenum disulfide ($\textrm{MoS}_{\textrm{2}}$) walls and in the presence of an external electric field…

Soft Condensed Matter · Physics 2023-12-04 S. M. Kazem Manzoorolajdad , Hossein Hamzehpour , Jalal Sarabadani

The Casimir interaction between two thin material films, between a film and a thick plate and between two films deposited on substrates is considered at large separations (high temperatures) which correspond to the classical limit. It is…

Other Condensed Matter · Physics 2014-01-10 G. L. Klimchitskaya , V. M. Mostepanenko

We formulate a general mean-field theory of a flat electric double layer in ionic liquids and electrolyte solutions with ions possessing static polarizability and a permanent dipole moment on a charged electrode. We establish a new…

Statistical Mechanics · Physics 2021-08-17 Yu. A. Budkov , S. V. Zavarzin , A. L. Kolesnikov

A simple model to describe Mixed Ionic Electronic Conductors (MIEC) in terms of standard semiconductor physics is described. This model allows to understand defect equilibrium and charge transport at ideal heterojunctions between materials…

Materials Science · Physics 2013-07-26 J. Roqueta , A. Apostolidis , J. Chaigneau , R. Moreno , J. Zapata , M. Burriel , J. Santiso

The Bragg-Williams free energy is used to incorporate nearest-neighbor interactions into the lattice gas model of a solvent-free ionic liquid near a planar electrode. We calculate the differential capacitance from solutions of the…

Chemical Physics · Physics 2018-12-04 Rachel Downing , Bjorn K. Berntson , Guilherme V. Bossa , Sylvio May

The effects of neutron irradiation on normal state and superconducting properties of epitaxial magnesium diboride thin films are studied up to fluences of 1020 cm-2. All the properties of the films change systematically upon irradiation.…

In this Letter we investigate the rupture instability of thin liquid films by means of a bifurcation analysis in the vicinity of the short-scale instability threshold. The rupture time estimate obtained in closed form as a function of the…

Fluid Dynamics · Physics 2009-11-10 A. M. Leshansky , B. Y. Rubinstein

We study a model for thin film electrodeposition in which instability development by preferential adsorption and reduction of cations at surface peaks competes with surface relaxation by diffusion of the adsorbates. The model considers…

Materials Science · Physics 2019-03-05 F. D. A. Aarão Reis , Dung di Caprio , Abdelhafed Taleb

There is a classic alternative to the Franck-Hertz experiment designed to show more than a recurrence of the first excited state. Instead of being subjected to a rising potential between source and accelerating grid, electrons are now…

Plasma Physics · Physics 2007-05-23 Peter Nicoletopoulos

We investigated the temperature dependence of the conductance fluctuations in thin films of the quasi-two-dimensional 1T-TaS$_2$ van der Waals material. The conductance fluctuations, determined from the derivative current-voltage…

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