Related papers: Electrochemical Thin Films At and Above the Classi…
The dc response of an electrochemical thin film, such as the separator in a micro-battery, is analyzed by solving the Poisson-Nernst-Planck equations, subject to boundary conditions appropriate for an electrolytic/galvanic cell. The model…
We consider the steady state limiting current that can be carried by an infinite periodic array of thin electron sheets spaced by period p in a planar diode of gap voltage V and gap separation d. Our primary assumptions are (1) electron…
We present theoretical models for the time-dependent voltage of an electrochemical cell in response to a current step, including effects of diffuse charge (or "space charge") near the electrodes on Faradaic reaction kinetics. The full model…
The response of a model micro-electrochemical system to a time-dependent applied voltage is analyzed. The article begins with a fresh historical review including electrochemistry, colloidal science, and microfluidics. The model problem…
Finite element modeling of charged species transport has enabled analysis, design, and optimization of a diverse array of electrochemical and electrokinetic devices. These systems are represented by the Poisson-Nernst-Planck equations…
Electrochemical phenomena in biology often unfold in confined geometries where micrometer- to millimeter-scale domains coexist with nanometer-scale interfacial diffuse charge layers. We analyze a model lipid membrane-electrolyte system…
We investigate the subtle effects of diffuse charge on interfacial kinetics by solving the governing equations for ion transport (Nernst-Planck) with realistic boundary conditions representing reaction kinetics (Butler-Volmer) and…
For the structure of the thin electrical double layer~(EDL) and the property related to the EDL capacitance, we analyze boundary layer solutions (corresponding to the electrostatic potential) of a non-local elliptic equation which is a…
We consider a mathematical model that describes the flow of a Nematic Liquid Crystal (NLC) film placed on a flat substrate, across which a spatially-varying electric potential is applied. Due to their polar nature, NLC molecules interact…
An immobile charged species provides a charged medium for transport of charge carriers that is exploited in many applications, such as permselective membranes, doped semiconductors, biological ion channels, as well as porous media and…
The maximum current that can be transported across a vacuum diode is limited by forces arising due to space charge. In a planar diode configuration, the space charge limited (SCL) current density from a planar emitting patch is given by the…
A transient Poisson-Nernst-Planck system with steric effects is analyzed in a bounded domain with no-flux boundary conditions for the ion concentrations and mixed Dirichlet-Neumann boundary conditions for the electric potential. The steric…
We analyze the simplest problem of electrochemical relaxation in more than one dimension - the response of an uncharged, ideally polarizable metallic sphere (or cylinder) in a symmetric, binary electrolyte to a uniform electric field. In…
Superconducting thin metallic films, functioning as supercurrent gate-tunable transistors, have considerable potential for future quantum electronic devices. Despite extensive research, a comprehensive microscopic quantitative mechanism…
The space-charge-limited current in a zero thickness planar thin film depends on the geometry of the electrodes. We present a theory which is to a large extent analytical and applicable to many different lay-outs. We show that a…
Non-equilibrium electrochemistry raises new challenges for atomistic simulation: we need to perform molecular dynamics for the nuclear degrees of freedom with an explicit description of the electrons, which in turn must be free to enter and…
Understanding over-limiting current (faster than diffusion) is a long-standing challenge in electrochemistry with applications in desalination and energy storage. Known mechanisms involve either chemical or hydrodynamic instabilities in…
Electrochemical devices often consist of multicomponent electrolyte solutions. Two processes influence the overall dynamics of these devices: the formation of electrical double layers and chemical conversion due to redox reactions. However,…
An approximate analytic theory is developed and implemented numerically for calculating the space charge limited current and electric field of a thin cylindrical beam or current sheet between two wide parallel electrodes. The flow is…
We revisit the classical problem of diffusion-limited ion transport to a membrane (or electrode) by considering the effects of charged side walls. Using simple mathematical models and numerical simulations, we identify three basic…